Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation

P. Smart; C A Mason; J R Loader; Anthony J.H.M.  Meijer; Alastair Florence; Kenneth Shankland; Ashleigh Fletcher; S P Thompson; Michela Brunelli; A H Hill; Lee Brammer

doi:10.1002/chem.201204492

Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation

P. Smart, C A Mason, J R Loader, Anthony J.H.M. Meijer, Alastair Florence, Kenneth Shankland, Ashleigh Fletcher, S P Thompson, Michela Brunelli, A H Hill, Lee Brammer^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

MOF zipper: Thermal removal of axial pyridine ligands from the non-covalently pillared metal-organic framework [Zn₂(camph) ₂(py)₂]×2EtOH prompts migration of alternate camphorate ligands to zip Zn centers from adjacent layers into continuous chains within the nonporous material [Zn₂(camph)₂] (see scheme). Unzipping to generate new pillared, layered MOFs occurs on exposure to new axial ligands.

Original language	English
Pages (from-to)	3552-3557
Number of pages	6
Journal	Chemistry - A European Journal
Volume	19
Issue number	11
DOIs	https://doi.org/10.1002/chem.201204492
Publication status	Published - 11 Mar 2013

Keywords

solid-state reactions
X-ray diffraction
density functional calculations
metal–organic frameworks
post-synthetic modification

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/chem.201204492

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Smart, P., Mason, C. A., Loader, J. R., Meijer, A. J. H. M., Florence, A., Shankland, K., Fletcher, A., Thompson, S. P., Brunelli, M., Hill, A. H., & Brammer, L. (2013). Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation. Chemistry - A European Journal , 19(11), 3552-3557. https://doi.org/10.1002/chem.201204492

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abstract = "MOF zipper: Thermal removal of axial pyridine ligands from the non-covalently pillared metal-organic framework [Zn2(camph) 2(py)2]×2EtOH prompts migration of alternate camphorate ligands to zip Zn centers from adjacent layers into continuous chains within the nonporous material [Zn2(camph)2] (see scheme). Unzipping to generate new pillared, layered MOFs occurs on exposure to new axial ligands. ",

keywords = "solid-state reactions, X-ray diffraction, density functional calculations, metal–organic frameworks, post-synthetic modification",

author = "P. Smart and Mason, {C A} and Loader, {J R} and Meijer, {Anthony J.H.M.} and Alastair Florence and Kenneth Shankland and Ashleigh Fletcher and Thompson, {S P} and Michela Brunelli and Hill, {A H} and Lee Brammer",

year = "2013",

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doi = "10.1002/chem.201204492",

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Smart, P, Mason, CA, Loader, JR, Meijer, AJHM, Florence, A, Shankland, K, Fletcher, A, Thompson, SP, Brunelli, M, Hill, AH & Brammer, L 2013, 'Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation', Chemistry - A European Journal , vol. 19, no. 11, pp. 3552-3557. https://doi.org/10.1002/chem.201204492

TY - JOUR

T1 - Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation

AU - Smart, P.

AU - Mason, C A

AU - Loader, J R

AU - Meijer, Anthony J.H.M.

AU - Florence, Alastair

AU - Shankland, Kenneth

AU - Fletcher, Ashleigh

AU - Thompson, S P

AU - Brunelli, Michela

AU - Hill, A H

AU - Brammer, Lee

PY - 2013/3/11

Y1 - 2013/3/11

N2 - MOF zipper: Thermal removal of axial pyridine ligands from the non-covalently pillared metal-organic framework [Zn2(camph) 2(py)2]×2EtOH prompts migration of alternate camphorate ligands to zip Zn centers from adjacent layers into continuous chains within the nonporous material [Zn2(camph)2] (see scheme). Unzipping to generate new pillared, layered MOFs occurs on exposure to new axial ligands.

AB - MOF zipper: Thermal removal of axial pyridine ligands from the non-covalently pillared metal-organic framework [Zn2(camph) 2(py)2]×2EtOH prompts migration of alternate camphorate ligands to zip Zn centers from adjacent layers into continuous chains within the nonporous material [Zn2(camph)2] (see scheme). Unzipping to generate new pillared, layered MOFs occurs on exposure to new axial ligands.

KW - solid-state reactions

KW - X-ray diffraction

KW - density functional calculations

KW - metal–organic frameworks

KW - post-synthetic modification

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AN - SCOPUS:84874595694

SN - 0947-6539

VL - 19

SP - 3552

EP - 3557

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 11

ER -

Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation

Abstract

Keywords

UN SDGs

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