(Z)-N-(2-Iodophenyl)-4-nitrobenzimidoyl cyanide

Rodolfo Moreno-Fuquen, Andres C Garcia, Rodrigo Abonia, Luz M Jaramillo-Gomez, Alan R. Kennedy

Research output: Contribution to journalArticle

Abstract

In the title molecule, C14H8IN3O2, the cyanide group is anti to the iodide
substituent of the adjacent benzene ring. The central segment is essentially
planar (r.m.s deviation = 0.0341 A ° ) and it is twisted away from the iodide- and
nitro-substituted benzene rings by 69.02 (9) and 15.83 (16), respectively. In the
crystal, molecules are linked by weak C—H N interactions, leading to C(8)
chains along [010].
LanguageEnglish
Pagesx160315
Number of pages3
JournalIUCr Data
Volume1
Issue number2
DOIs
Publication statusPublished - 27 Feb 2016

Fingerprint

Cyanides
Benzene
Molecules
Iodides

Keywords

  • crystal structure
  • C—H⋯N inter­actions
  • α-imino­nitrile

Cite this

Moreno-Fuquen, R., Garcia, A. C., Abonia, R., Jaramillo-Gomez, L. M., & Kennedy, A. R. (2016). (Z)-N-(2-Iodophenyl)-4-nitrobenzimidoyl cyanide. IUCr Data, 1(2), x160315. https://doi.org/10.1107/S2414314616003151
Moreno-Fuquen, Rodolfo ; Garcia, Andres C ; Abonia, Rodrigo ; Jaramillo-Gomez, Luz M ; Kennedy, Alan R. / (Z)-N-(2-Iodophenyl)-4-nitrobenzimidoyl cyanide. In: IUCr Data. 2016 ; Vol. 1, No. 2. pp. x160315.
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abstract = "In the title molecule, C14H8IN3O2, the cyanide group is anti to the iodidesubstituent of the adjacent benzene ring. The central segment is essentiallyplanar (r.m.s deviation = 0.0341 A ° ) and it is twisted away from the iodide- andnitro-substituted benzene rings by 69.02 (9) and 15.83 (16), respectively. In thecrystal, molecules are linked by weak C—H N interactions, leading to C(8)chains along [010].",
keywords = "crystal structure, C—H⋯N inter­actions, α-imino­nitrile",
author = "Rodolfo Moreno-Fuquen and Garcia, {Andres C} and Rodrigo Abonia and Jaramillo-Gomez, {Luz M} and Kennedy, {Alan R.}",
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Moreno-Fuquen, R, Garcia, AC, Abonia, R, Jaramillo-Gomez, LM & Kennedy, AR 2016, '(Z)-N-(2-Iodophenyl)-4-nitrobenzimidoyl cyanide' IUCr Data, vol. 1, no. 2, pp. x160315. https://doi.org/10.1107/S2414314616003151

(Z)-N-(2-Iodophenyl)-4-nitrobenzimidoyl cyanide. / Moreno-Fuquen, Rodolfo; Garcia, Andres C; Abonia, Rodrigo; Jaramillo-Gomez, Luz M; Kennedy, Alan R.

In: IUCr Data, Vol. 1, No. 2, 27.02.2016, p. x160315.

Research output: Contribution to journalArticle

TY - JOUR

T1 - (Z)-N-(2-Iodophenyl)-4-nitrobenzimidoyl cyanide

AU - Moreno-Fuquen, Rodolfo

AU - Garcia, Andres C

AU - Abonia, Rodrigo

AU - Jaramillo-Gomez, Luz M

AU - Kennedy, Alan R.

N1 - Open access journal. As discussed previously for the sister journal Acta Cryst. Section E, the author proofs are in cif format that is currently unsupported by PURE.

PY - 2016/2/27

Y1 - 2016/2/27

N2 - In the title molecule, C14H8IN3O2, the cyanide group is anti to the iodidesubstituent of the adjacent benzene ring. The central segment is essentiallyplanar (r.m.s deviation = 0.0341 A ° ) and it is twisted away from the iodide- andnitro-substituted benzene rings by 69.02 (9) and 15.83 (16), respectively. In thecrystal, molecules are linked by weak C—H N interactions, leading to C(8)chains along [010].

AB - In the title molecule, C14H8IN3O2, the cyanide group is anti to the iodidesubstituent of the adjacent benzene ring. The central segment is essentiallyplanar (r.m.s deviation = 0.0341 A ° ) and it is twisted away from the iodide- andnitro-substituted benzene rings by 69.02 (9) and 15.83 (16), respectively. In thecrystal, molecules are linked by weak C—H N interactions, leading to C(8)chains along [010].

KW - crystal structure

KW - C—H⋯N inter­actions

KW - α-imino­nitrile

U2 - 10.1107/S2414314616003151

DO - 10.1107/S2414314616003151

M3 - Article

VL - 1

SP - x160315

JO - IUCr Data

T2 - IUCr Data

JF - IUCr Data

SN - 2414-3146

IS - 2

ER -

Moreno-Fuquen R, Garcia AC, Abonia R, Jaramillo-Gomez LM, Kennedy AR. (Z)-N-(2-Iodophenyl)-4-nitrobenzimidoyl cyanide. IUCr Data. 2016 Feb 27;1(2):x160315. https://doi.org/10.1107/S2414314616003151