X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding

D BARR, W CLEGG, Robert Mulvey, R SNAITH

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Abstract

An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.
LanguageEnglish
Pages226-227
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - 1984

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Lithium
Anions
Nitrogen
X-Rays

Keywords

  • crystal structures
  • x-rays
  • lithium bonding

Cite this

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title = "X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding",
abstract = "An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.",
keywords = "crystal structures, x-rays, lithium bonding",
author = "D BARR and W CLEGG and Robert Mulvey and R SNAITH",
year = "1984",
doi = "10.1039/C39840000226",
language = "English",
pages = "226--227",
journal = "Journal of the Chemical Society, Chemical Communications",
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T1 - X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding

AU - BARR, D

AU - CLEGG, W

AU - Mulvey, Robert

AU - SNAITH, R

PY - 1984

Y1 - 1984

N2 - An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.

AB - An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.

KW - crystal structures

KW - x-rays

KW - lithium bonding

U2 - 10.1039/C39840000226

DO - 10.1039/C39840000226

M3 - Article

SP - 226

EP - 227

JO - Journal of the Chemical Society, Chemical Communications

T2 - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

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ER -