X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding

D BARR, W CLEGG, Robert Mulvey, R SNAITH

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Abstract

An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.
Original languageEnglish
Pages (from-to)226-227
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - 1984

Keywords

  • crystal structures
  • x-rays
  • lithium bonding

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