X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding

D  BARR; W  CLEGG; Robert Mulvey; R  SNAITH

doi:10.1039/C39840000226

X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding

D BARR, W CLEGG, Robert Mulvey, R SNAITH

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.

Original language	English
Pages (from-to)	226-227
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39840000226
Publication status	Published - 1984

Keywords

crystal structures
x-rays
lithium bonding

Access to Document

10.1039/C39840000226

Cite this

BARR, D., CLEGG, W., Mulvey, R., & SNAITH, R. (1984). X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding. Journal of the Chemical Society, Chemical Communications, (4), 226-227. https://doi.org/10.1039/C39840000226

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title = "X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding",

abstract = "An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.",

keywords = "crystal structures, x-rays, lithium bonding",

author = "D BARR and W CLEGG and Robert Mulvey and R SNAITH",

year = "1984",

doi = "10.1039/C39840000226",

language = "English",

pages = "226--227",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "4",

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BARR, D, CLEGG, W, Mulvey, R & SNAITH, R 1984, 'X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding', Journal of the Chemical Society, Chemical Communications, no. 4, pp. 226-227. https://doi.org/10.1039/C39840000226

X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding. / BARR, D ; CLEGG, W ; Mulvey, Robert; SNAITH, R .

In: Journal of the Chemical Society, Chemical Communications, No. 4, 1984, p. 226-227.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding

AU - BARR, D

AU - CLEGG, W

AU - Mulvey, Robert

AU - SNAITH, R

PY - 1984

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N2 - An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.

AB - An X-ray crystallographic study of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–, (1), has shown it to be a clustered lithium 'ate complex, with an unprecedented pentanuclear Li5 clustered-anion having both µ2 edge and µ3 face nitrogen to lithium bonding.

KW - crystal structures

KW - x-rays

KW - lithium bonding

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DO - 10.1039/C39840000226

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SP - 226

EP - 227

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

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