Volumetric intensity dependence on the formation of molecular and atomic ions within a high intensity laser focus

Lynne Robson, Kenneth W.D. Ledingham, Paul McKenna, Thomas McCanny, Seiji Shimizu, Jiamin M. Yang, Claes-Göran Wahlström, Rodrigo Lopez-Martens, Katalin Varju, Per Johnsson, Johan Mauritsson

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The mechanism of atomic and molecular ionization in intense, ultra-short laser fields is a subject which continues to receive considerable attention. An inherent difficulty with techniques involving the tight focus of a laser beam is the continuous distribution of intensities contained within the focus, which can vary over several orders of magnitude. The present study adopts time of flight mass spectrometry coupled with a high intensity (8 × 1015 Wcm−2), ultra-short (20 fs) pulse laser in order to investigate the ionization and dissociation of the aromatic molecule benzene-d1 (C6H5D) as a function of intensity within a focused laser beam, by scanning the laser focus in the direction of propagation, while detecting ions produced only in a "thin" slice (400 and 800 μm) of the focus. The resultant TOF mass spectra varies significantly, highlighting the dependence on the range of specific intensities accessed and their volumetric weightings on the ionization/dissociation pathways accessed.
LanguageEnglish
Pages82-89
Number of pages7
JournalJournal of the American Society for Mass Spectrometry
Volume16
Issue number1
DOIs
Publication statusPublished - Jan 2005

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Ionization
Lasers
Ions
Laser beams
Benzene
Mass spectrometry
Laser pulses
Scanning
Molecules
Mass Spectrometry
Direction compound

Keywords

  • ions
  • lasers
  • molecular ionization
  • atomic ionization

Cite this

Robson, Lynne ; Ledingham, Kenneth W.D. ; McKenna, Paul ; McCanny, Thomas ; Shimizu, Seiji ; Yang, Jiamin M. ; Wahlström, Claes-Göran ; Lopez-Martens, Rodrigo ; Varju, Katalin ; Johnsson, Per ; Mauritsson, Johan. / Volumetric intensity dependence on the formation of molecular and atomic ions within a high intensity laser focus. In: Journal of the American Society for Mass Spectrometry. 2005 ; Vol. 16, No. 1. pp. 82-89.
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Volumetric intensity dependence on the formation of molecular and atomic ions within a high intensity laser focus. / Robson, Lynne; Ledingham, Kenneth W.D.; McKenna, Paul; McCanny, Thomas; Shimizu, Seiji; Yang, Jiamin M.; Wahlström, Claes-Göran; Lopez-Martens, Rodrigo; Varju, Katalin; Johnsson, Per; Mauritsson, Johan.

In: Journal of the American Society for Mass Spectrometry, Vol. 16, No. 1, 01.2005, p. 82-89.

Research output: Contribution to journalArticle

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AU - McKenna, Paul

AU - McCanny, Thomas

AU - Shimizu, Seiji

AU - Yang, Jiamin M.

AU - Wahlström, Claes-Göran

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AU - Johnsson, Per

AU - Mauritsson, Johan

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AB - The mechanism of atomic and molecular ionization in intense, ultra-short laser fields is a subject which continues to receive considerable attention. An inherent difficulty with techniques involving the tight focus of a laser beam is the continuous distribution of intensities contained within the focus, which can vary over several orders of magnitude. The present study adopts time of flight mass spectrometry coupled with a high intensity (8 × 1015 Wcm−2), ultra-short (20 fs) pulse laser in order to investigate the ionization and dissociation of the aromatic molecule benzene-d1 (C6H5D) as a function of intensity within a focused laser beam, by scanning the laser focus in the direction of propagation, while detecting ions produced only in a "thin" slice (400 and 800 μm) of the focus. The resultant TOF mass spectra varies significantly, highlighting the dependence on the range of specific intensities accessed and their volumetric weightings on the ionization/dissociation pathways accessed.

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