Vibrational spectra of EDTA complexes of divalent tin and lead

R.H. Nuttall, A.A. McConnell

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The vibrational spectra of Na2SnEDTA·2H2O and Na2PbEDTA·2H2O in solution, and as solids, suggest that the species present in the two phases are essentially similar. The spectra can be assigned on the basis of a C2υψ-heptaco-ordinate arrangement about the metal. Comparison with the vibrational spectra of binuclear tin and lead complexes suggests that Pb2EDTA has a similar structure to that established for Sn2EDTA·2H2O, but with slight changes in bond distances.
LanguageEnglish
Pages459-462
Number of pages3
JournalSpectrochimica acta. Part A: Molecular spectroscopy
Volume33
Issue number3-4
DOIs
Publication statusPublished - 1977

Fingerprint

Ethylenediaminetetraacetic acid
Vibrational spectra
Tin
Lead
Metals

Keywords

  • vibrational-spectra
  • EDTA
  • tin
  • lead

Cite this

Nuttall, R.H. ; McConnell, A.A. / Vibrational spectra of EDTA complexes of divalent tin and lead. In: Spectrochimica acta. Part A: Molecular spectroscopy. 1977 ; Vol. 33, No. 3-4. pp. 459-462.
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Vibrational spectra of EDTA complexes of divalent tin and lead. / Nuttall, R.H.; McConnell, A.A.

In: Spectrochimica acta. Part A: Molecular spectroscopy, Vol. 33, No. 3-4, 1977, p. 459-462.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Vibrational spectra of EDTA complexes of divalent tin and lead

AU - Nuttall, R.H.

AU - McConnell, A.A.

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AB - The vibrational spectra of Na2SnEDTA·2H2O and Na2PbEDTA·2H2O in solution, and as solids, suggest that the species present in the two phases are essentially similar. The spectra can be assigned on the basis of a C2υψ-heptaco-ordinate arrangement about the metal. Comparison with the vibrational spectra of binuclear tin and lead complexes suggests that Pb2EDTA has a similar structure to that established for Sn2EDTA·2H2O, but with slight changes in bond distances.

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KW - EDTA

KW - tin

KW - lead

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