Vibrational and NMR spectra of bidentate EDTA complexes of palladium(ii)

R.H. Nuttall; A.A. McConnell

doi:10.1016/S0020-1693(00)91105-8

Vibrational and NMR spectra of bidentate EDTA complexes of palladium(ii)

R.H. Nuttall, A.A. McConnell

Pure And Applied Chemistry

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

The vibrational spectra of H4EDTAPdCl2·5H2O and its aqueous solutions indicate that EDTA acts as a bidentate ligand. NMR spectra of the D2O solutions at varying pD support the formulation of the solution species as hydrolysis products, involving aquo and hydroxy species, In which EDTA is exclusively bidentate.

Original language	English
Pages (from-to)	253-256
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	19
Issue number	3
DOIs	https://doi.org/10.1016/S0020-1693(00)91105-8
Publication status	Published - 1976

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Keywords

vibrational spectra
aqueous solutions
EDTA
bidentate ligand
NMR spectra
hydrolysis products

Cite this

Nuttall, R. H., & McConnell, A. A. (1976). Vibrational and NMR spectra of bidentate EDTA complexes of palladium(ii). Inorganica Chimica Acta, 19(3), 253-256. https://doi.org/10.1016/S0020-1693(00)91105-8

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abstract = "The vibrational spectra of H4EDTAPdCl2·5H2O and its aqueous solutions indicate that EDTA acts as a bidentate ligand. NMR spectra of the D2O solutions at varying pD support the formulation of the solution species as hydrolysis products, involving aquo and hydroxy species, In which EDTA is exclusively bidentate.",

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AU - Nuttall, R.H.

AU - McConnell, A.A.

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N2 - The vibrational spectra of H4EDTAPdCl2·5H2O and its aqueous solutions indicate that EDTA acts as a bidentate ligand. NMR spectra of the D2O solutions at varying pD support the formulation of the solution species as hydrolysis products, involving aquo and hydroxy species, In which EDTA is exclusively bidentate.

AB - The vibrational spectra of H4EDTAPdCl2·5H2O and its aqueous solutions indicate that EDTA acts as a bidentate ligand. NMR spectra of the D2O solutions at varying pD support the formulation of the solution species as hydrolysis products, involving aquo and hydroxy species, In which EDTA is exclusively bidentate.

KW - vibrational spectra

KW - aqueous solutions

KW - EDTA

KW - bidentate ligand

KW - NMR spectra

KW - hydrolysis products

UR - http://dx.doi.org/10.1016/S0020-1693(00)91105-8

U2 - 10.1016/S0020-1693(00)91105-8

DO - 10.1016/S0020-1693(00)91105-8

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Access to Document

10.1016/S0020-1693(00)91105-8

http://dx.doi.org/10.1016/S0020-1693(00)91105-8