Unmasking representative structures of tmp-active hauser and turbo-hauser bases

P. Garcia-Alvarez, D.V. Graham, E. Hevia, A.R. Kennedy, J. Klett, R.E. Mulvey, C.T. O'Hara, Susan Weatherstone

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Abstract

The molecular engines that drive enhanced magnesiations are unveiled through structural elucidation of a 2,2,6,6-tetramethylpiperidide (TMP) Hauser base and its turbo model (see structure; Mg green, Li violet, C purple, O red, N blue, Cl yellow).
Original languageEnglish
Pages (from-to)8079-8081
Number of pages3
JournalAngewandte Chemie
Volume47
Issue number42
DOIs
Publication statusPublished - 6 Oct 2008

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Keywords

  • Grignard reagents
  • Hauser bases
  • lithium
  • magnesium
  • regioselectivity

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