Unmasking representative structures of tmp-active hauser and turbo-hauser bases

P. Garcia-Alvarez; D.V. Graham; E. Hevia; A.R. Kennedy; J. Klett; R.E. Mulvey; C.T. O'Hara; Susan Weatherstone

doi:10.1002/anie.200802618

Unmasking representative structures of tmp-active hauser and turbo-hauser bases

P. Garcia-Alvarez, D.V. Graham, E. Hevia, A.R. Kennedy, J. Klett, R.E. Mulvey, C.T. O'Hara, Susan Weatherstone

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

111 Citations (Scopus)

Abstract

The molecular engines that drive enhanced magnesiations are unveiled through structural elucidation of a 2,2,6,6-tetramethylpiperidide (TMP) Hauser base and its turbo model (see structure; Mg green, Li violet, C purple, O red, N blue, Cl yellow).

Original language	English
Pages (from-to)	8079-8081
Number of pages	3
Journal	Angewandte Chemie
Volume	47
Issue number	42
DOIs	https://doi.org/10.1002/anie.200802618
Publication status	Published - 6 Oct 2008

Keywords

Grignard reagents
Hauser bases
lithium
magnesium
regioselectivity

Access to Document

10.1002/anie.200802618

Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)
Murphy, J., Coombs, G., Ferguson, A. & Florence, A.
Scottish Funding Council SFC, EPSRC (Engineering and Physical Sciences Research Council)
1/09/07 → 30/10/12
Project: Research
"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY
Mulvey, R.
EPSRC (Engineering and Physical Sciences Research Council)
1/10/06 → 31/03/10
Project: Research
Mixed-Metal Molecular Synergy and its Application in Inverse Crown Chemistry
Mulvey, R.
EPSRC (Engineering and Physical Sciences Research Council)
1/01/05 → 31/01/09
Project: Research

x-ray diffractometer
Alan Kennedy
Pure And Applied Chemistry
Facility/equipment: Equipment

Cite this

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abstract = "The molecular engines that drive enhanced magnesiations are unveiled through structural elucidation of a 2,2,6,6-tetramethylpiperidide (TMP) Hauser base and its turbo model (see structure; Mg green, Li violet, C purple, O red, N blue, Cl yellow).",

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AU - Garcia-Alvarez, P.

AU - Graham, D.V.

AU - Hevia, E.

AU - Kennedy, A.R.

AU - Klett, J.

AU - Mulvey, R.E.

AU - O'Hara, C.T.

AU - Weatherstone, Susan

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AB - The molecular engines that drive enhanced magnesiations are unveiled through structural elucidation of a 2,2,6,6-tetramethylpiperidide (TMP) Hauser base and its turbo model (see structure; Mg green, Li violet, C purple, O red, N blue, Cl yellow).

KW - Grignard reagents

KW - Hauser bases

KW - lithium

KW - magnesium

KW - regioselectivity

U2 - 10.1002/anie.200802618

DO - 10.1002/anie.200802618

M3 - Article

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VL - 47

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EP - 8081

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 42

ER -

Unmasking representative structures of tmp-active hauser and turbo-hauser bases

Abstract

Keywords

Access to Document

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Projects

Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)

"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

Mixed-Metal Molecular Synergy and its Application in Inverse Crown Chemistry

Equipment

x-ray diffractometer

Cite this