Unmasking representative structures of tmp-active hauser and turbo-hauser bases

P. Garcia-Alvarez, D.V. Graham, E. Hevia, A.R. Kennedy, J. Klett, R.E. Mulvey, C.T. O'Hara, Susan Weatherstone

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

The molecular engines that drive enhanced magnesiations are unveiled through structural elucidation of a 2,2,6,6-tetramethylpiperidide (TMP) Hauser base and its turbo model (see structure; Mg green, Li violet, C purple, O red, N blue, Cl yellow).
LanguageEnglish
Pages8079-8081
Number of pages3
JournalAngewandte Chemie
Volume47
Issue number42
DOIs
Publication statusPublished - 6 Oct 2008

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2,2,6,6-tetramethylpiperidide

Keywords

  • Grignard reagents
  • Hauser bases
  • lithium
  • magnesium
  • regioselectivity

Cite this

Garcia-Alvarez, P. ; Graham, D.V. ; Hevia, E. ; Kennedy, A.R. ; Klett, J. ; Mulvey, R.E. ; O'Hara, C.T. ; Weatherstone, Susan. / Unmasking representative structures of tmp-active hauser and turbo-hauser bases. In: Angewandte Chemie. 2008 ; Vol. 47, No. 42. pp. 8079-8081.
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Unmasking representative structures of tmp-active hauser and turbo-hauser bases. / Garcia-Alvarez, P.; Graham, D.V.; Hevia, E.; Kennedy, A.R.; Klett, J.; Mulvey, R.E.; O'Hara, C.T.; Weatherstone, Susan.

In: Angewandte Chemie, Vol. 47, No. 42, 06.10.2008, p. 8079-8081.

Research output: Contribution to journalArticle

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