Two-photon spectroscopy of cyclometalated iridium complexes

Robert M. Edkins; Sylvia L. Bettington; Andrés E. Goeta; Andrew Beeby

doi:10.1039/c1dt11164g

Two-photon spectroscopy of cyclometalated iridium complexes

Robert M. Edkins, Sylvia L. Bettington, Andrés E. Goeta, Andrew Beeby^*

^*Corresponding author for this work

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

The near-infrared two-photon absorption (TPA) spectra of a series of cyclometalated iridium complexes have been measured. These complexes exhibit moderately large TPA cross-sections of approximately 20 GM at the biological relevant wavelength of 800 nm. A new complex has been designed and synthesised, and found to have an increased cross-section of 44 GM at 800 nm. Full photophysical characterisation of this complex is presented.

Original language	English
Pages (from-to)	12765-12770
Number of pages	6
Journal	Dalton Transactions
Volume	40
Issue number	47
DOIs	https://doi.org/10.1039/c1dt11164g
Publication status	Published - 21 Dec 2011

Keywords

two-photon absorption
iridium complexes
spectroscopy

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10.1039/c1dt11164g

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abstract = "The near-infrared two-photon absorption (TPA) spectra of a series of cyclometalated iridium complexes have been measured. These complexes exhibit moderately large TPA cross-sections of approximately 20 GM at the biological relevant wavelength of 800 nm. A new complex has been designed and synthesised, and found to have an increased cross-section of 44 GM at 800 nm. Full photophysical characterisation of this complex is presented.",

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AU - Edkins, Robert M.

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AU - Goeta, Andrés E.

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PY - 2011/12/21

Y1 - 2011/12/21

N2 - The near-infrared two-photon absorption (TPA) spectra of a series of cyclometalated iridium complexes have been measured. These complexes exhibit moderately large TPA cross-sections of approximately 20 GM at the biological relevant wavelength of 800 nm. A new complex has been designed and synthesised, and found to have an increased cross-section of 44 GM at 800 nm. Full photophysical characterisation of this complex is presented.

AB - The near-infrared two-photon absorption (TPA) spectra of a series of cyclometalated iridium complexes have been measured. These complexes exhibit moderately large TPA cross-sections of approximately 20 GM at the biological relevant wavelength of 800 nm. A new complex has been designed and synthesised, and found to have an increased cross-section of 44 GM at 800 nm. Full photophysical characterisation of this complex is presented.

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KW - iridium complexes

KW - spectroscopy

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M3 - Article

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JO - Dalton Transactions

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Two-photon spectroscopy of cyclometalated iridium complexes

Abstract

Keywords

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