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Twelve-connected porous metal–organic frameworks with high H2 adsorption

  • J. Jia
  • , X. Lin
  • , A. J. Blake
  • , N. R. Champness
  • , P. Hubberstey
  • , G. Walker
  • , Eddie Cussen
  • , M. Schroder

Research output: Contribution to journalArticlepeer-review

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Abstract

The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3]·n(solv)}∞1 and {[Fe3(O)(L)3]·n(solv)}∞2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.
Original languageEnglish
Pages (from-to)840-842
Number of pages3
JournalChemical Communications (London)
Volume2007
Issue number8
Early online date7 Dec 2006
DOIs
Publication statusPublished - 2007

Keywords

  • metals
  • metal–organic frameworks
  • adsorption

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