Twelve-connected porous metal–organic frameworks with high H2 adsorption

J. Jia, X. Lin, A. J. Blake, N. R. Champness, P. Hubberstey, G. Walker, Eddie Cussen, M. Schroder

Research output: Contribution to journalArticlepeer-review

212 Citations (Scopus)
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Abstract

The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3]·n(solv)}∞1 and {[Fe3(O)(L)3]·n(solv)}∞2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.
Original languageEnglish
Pages (from-to)840-842
Number of pages3
JournalChemical Communications (London)
Volume2007
Issue number8
Early online date7 Dec 2006
DOIs
Publication statusPublished - 2007

Keywords

  • metals
  • metal–organic frameworks
  • adsorption

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