Twelve-connected porous metal–organic frameworks with high H2 adsorption

J. Jia; X. Lin; A. J. Blake; N. R. Champness; P. Hubberstey; G. Walker; Eddie Cussen; M. Schroder

doi:10.1039/B614254K

Twelve-connected porous metal–organic frameworks with high H2 adsorption

J. Jia, X. Lin, A. J. Blake, N. R. Champness, P. Hubberstey, G. Walker, Eddie Cussen, M. Schroder

Pure And Applied Chemistry

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Abstract

The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3]·n(solv)}∞1 and {[Fe3(O)(L)3]·n(solv)}∞2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.

Original language	English
Pages (from-to)	840-842
Number of pages	3
Journal	Chemical Communications (London)
Volume	2007
Issue number	8
Early online date	7 Dec 2006
DOIs	https://doi.org/10.1039/B614254K
Publication status	Published - 2007

Keywords

metals
metal–organic frameworks
adsorption

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10.1039/B614254K

Chem Comm H stor SchroderFinal published version, 315 KB

Cite this

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title = "Twelve-connected porous metal–organic frameworks with high H2 adsorption",

abstract = "The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3]·n(solv)}∞1 and {[Fe3(O)(L)3]·n(solv)}∞2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.",

keywords = "metals, metal–organic frameworks , adsorption",

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T1 - Twelve-connected porous metal–organic frameworks with high H2 adsorption

AU - Jia, J.

AU - Lin, X.

AU - Blake, A. J.

AU - Champness, N. R.

AU - Hubberstey, P.

AU - Walker, G.

AU - Cussen, Eddie

AU - Schroder, M.

PY - 2007

Y1 - 2007

N2 - The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3]·n(solv)}∞1 and {[Fe3(O)(L)3]·n(solv)}∞2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.

AB - The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3]·n(solv)}∞1 and {[Fe3(O)(L)3]·n(solv)}∞2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.

KW - metals

KW - metal–organic frameworks

KW - adsorption

U2 - 10.1039/B614254K

DO - 10.1039/B614254K

M3 - Article

SN - 0009-241X

VL - 2007

SP - 840

EP - 842

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 8

ER -

Twelve-connected porous metal–organic frameworks with high H2 adsorption

Abstract

Keywords

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