Tuneable Fmoc–Phe–(4-X)–Phe–NH2 nanostructures by variable electronic substitution

Charalampos G Pappas; Yousef M Abul-Haija; Angela Flack; Pim W J M Frederix; Rein V Ulijn

doi:10.1039/c4cc04926h

Tuneable Fmoc–Phe–(4-X)–Phe–NH2 nanostructures by variable electronic substitution

Charalampos G Pappas, Yousef M Abul-Haija, Angela Flack, Pim W J M Frederix, Rein V Ulijn

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Abstract

Supramolecular structures were produced by in situ enzymatic condensation of Fmoc-Phe-(4-X), where X denotes electron withdrawing or donating groups, with Phe-NH2. The relative contribution of π-stacking and H-bonding interactions can be regulated by the nature of X, resulting in tuneable nanoscale morphologies.

Original language	English
Pages (from-to)	10630-10633
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	73
Early online date	23 Jul 2014
DOIs	https://doi.org/10.1039/c4cc04926h
Publication status	Published - 21 Sept 2014

Keywords

supramolecular structures
tunable nanostructures
tuneable nanoscale morphologies

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10.1039/c4cc04926h

Pappas-etal-nanostructures-by-variable-electronic-substitution-CC-2014Accepted author manuscript, 776 KB

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abstract = "Supramolecular structures were produced by in situ enzymatic condensation of Fmoc-Phe-(4-X), where X denotes electron withdrawing or donating groups, with Phe-NH2. The relative contribution of π-stacking and H-bonding interactions can be regulated by the nature of X, resulting in tuneable nanoscale morphologies.",

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AU - Pappas, Charalampos G

AU - Abul-Haija, Yousef M

AU - Flack, Angela

AU - Frederix, Pim W J M

AU - Ulijn, Rein V

PY - 2014/9/21

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AB - Supramolecular structures were produced by in situ enzymatic condensation of Fmoc-Phe-(4-X), where X denotes electron withdrawing or donating groups, with Phe-NH2. The relative contribution of π-stacking and H-bonding interactions can be regulated by the nature of X, resulting in tuneable nanoscale morphologies.

KW - supramolecular structures

KW - tunable nanostructures

KW - tuneable nanoscale morphologies

U2 - 10.1039/c4cc04926h

DO - 10.1039/c4cc04926h

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EP - 10633

JO - Chemical Communications

JF - Chemical Communications

IS - 73

ER -

Tuneable Fmoc–Phe–(4-X)–Phe–NH2 nanostructures by variable electronic substitution

Abstract

Keywords

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