Trends and prospects of bimetallic exsolution

Chenyang Tang; Kalliopi Kousi; Dragos Neagu; Ian S. Metcalfe

doi:10.1002/chem.202004950

Trends and prospects of bimetallic exsolution

Chenyang Tang, Kalliopi Kousi^*, Dragos Neagu, Ian S. Metcalfe

^*Corresponding author for this work

Chemical And Process Engineering

Research output: Contribution to journal › Review article › peer-review

42 Citations (Scopus)

33 Downloads (Pure)

Abstract

Supported bimetallic nanoparticles used for various chemical transformations appear to be more appealing than their monometallic counterparts, because of their unique properties mainly originating from the synergistic effects between the two different metals. Exsolution, a relatively new preparation method for supported nanoparticles, has earned increasing attention for bimetallic systems in the past decade, not only due to the high stability of the resulting nanoparticles but also for the potential to control key particle properties (size, composition, structure, morphology, etc.). In this review, we summarize the trends and advances on exsolution of bimetallic systems and provide prospects for future studies in this field.

Original language	English
Pages (from-to)	6666-6675
Number of pages	10
Journal	Chemistry - A European Journal
Volume	27
Issue number	22
Early online date	24 Feb 2021
DOIs	https://doi.org/10.1002/chem.202004950
Publication status	Published - 16 Apr 2021

Funding

The research leading to these results has received funding from the Engineering & Physical Sciences Research Council (EPSRC) via grants EP/P007767/1 and EP/P009050/1. EP/P024807/1 and EP/R023921/1. ISM acknowledges funding from the Royal Academy of Engineering through a Chair in Emerging Technologies award entitled “Engineering chemical reactor technologies for a low‐carbon energy future”, grant number CiET1819\2\57.

Keywords

bimetallic exsolution
catalysis
electrochemistry
energy conversion
nanomaterials

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10.1002/chem.202004950Licence: CC BY 4.0

Tang-etal-CEJ-2021-Trends-and-prospects-of-bimetallic-exsolutionFinal published version, 1.53 MBLicence: CC BY 4.0

Cite this

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title = "Trends and prospects of bimetallic exsolution",

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AU - Tang, Chenyang

AU - Kousi, Kalliopi

AU - Neagu, Dragos

AU - Metcalfe, Ian S.

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Y1 - 2021/4/16

N2 - Supported bimetallic nanoparticles used for various chemical transformations appear to be more appealing than their monometallic counterparts, because of their unique properties mainly originating from the synergistic effects between the two different metals. Exsolution, a relatively new preparation method for supported nanoparticles, has earned increasing attention for bimetallic systems in the past decade, not only due to the high stability of the resulting nanoparticles but also for the potential to control key particle properties (size, composition, structure, morphology, etc.). In this review, we summarize the trends and advances on exsolution of bimetallic systems and provide prospects for future studies in this field.

AB - Supported bimetallic nanoparticles used for various chemical transformations appear to be more appealing than their monometallic counterparts, because of their unique properties mainly originating from the synergistic effects between the two different metals. Exsolution, a relatively new preparation method for supported nanoparticles, has earned increasing attention for bimetallic systems in the past decade, not only due to the high stability of the resulting nanoparticles but also for the potential to control key particle properties (size, composition, structure, morphology, etc.). In this review, we summarize the trends and advances on exsolution of bimetallic systems and provide prospects for future studies in this field.

KW - bimetallic exsolution

KW - catalysis

KW - electrochemistry

KW - energy conversion

KW - nanomaterials

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JO - Chemistry - A European Journal

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ER -

Trends and prospects of bimetallic exsolution

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Proximity engineered ion transport for sustainable energy conversion

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Trends and prospects of bimetallic exsolution

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Proximity engineered ion transport for sustainable energy conversion

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