Projects per year
This study establishes a new trans-metal-trapping (TMT) protocol based on a mixture of LiTMP (the base) and tris(trimethylsilylmethyl)gallium [Ga(CH2SiMe3)3, GaR3] (the trap) that, operating in a tandem manner, is effective for the regioselective deprotonation of sensitive diazines in hydrocarbon solution as illustrated through reactions of pyrazine, pyridazine and pyrimidine, as well as through the N-S heterocycle benzothiazole, the metallo-activated complexes of all of which have been isolated and structurally defined.
- sensitive diazines
- LiTMP lithiation
FingerprintDive into the research topics of 'Transforming LiTMP lithiation of challenging diazines via gallium alkyl trans-metal-trapping'. Together they form a unique fingerprint.
- 2 Finished
Hevia, E. & Mulvey, R.
8/12/15 → 7/05/19
MIXMETAPPS: Tailoring Mixed-Metal Chemistry For Frontier Synthetic And Catalytic Applications (ERC Starting Grant)
1/10/11 → 31/03/17
Data for: "Transforming LiTMP lithiation of challenging diazines via gallium alkyl trans-metal-trapping"