trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults

R.J. Cross; A.R. Kennedy; K.W. Muir

doi:10.1107/S0108270194009042

trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults

R.J. Cross, A.R. Kennedy, K.W. Muir

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.

Original language	English
Pages (from-to)	208-210
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	51
Issue number	2
DOIs	https://doi.org/10.1107/S0108270194009042
Publication status	Published - 1995

Keywords

Pd atom
cr-tolyl
crystal
geometry

Access to Document

10.1107/S0108270194009042

x-ray diffractometer
Alan Kennedy
Pure And Applied Chemistry
Facility/equipment: Equipment

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title = "trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults",

abstract = "In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.",

keywords = "Pd atom, cr-tolyl, crystal, geometry",

author = "R.J. Cross and A.R. Kennedy and K.W. Muir",

year = "1995",

doi = "10.1107/S0108270194009042",

language = "English",

volume = "51",

pages = "208--210",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

number = "2",

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T1 - trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults

AU - Cross, R.J.

AU - Kennedy, A.R.

AU - Muir, K.W.

PY - 1995

Y1 - 1995

N2 - In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.

AB - In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.

KW - Pd atom

KW - cr-tolyl

KW - crystal

KW - geometry

U2 - 10.1107/S0108270194009042

DO - 10.1107/S0108270194009042

M3 - Article

SN - 0108-2701

VL - 51

SP - 208

EP - 210

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults

Abstract

Keywords

Access to Document

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Equipment

x-ray diffractometer

Cite this