trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults

R.J. Cross, A.R. Kennedy, K.W. Muir

Research output: Contribution to journalArticle

Abstract

In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.
Original languageEnglish
Pages (from-to)208-210
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume51
Issue number2
DOIs
Publication statusPublished - 1995

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Stacking faults
Crystals
Atoms
Geometry
bis(triphenylphosphine)palladium(II)

Keywords

  • Pd atom
  • cr-tolyl
  • crystal
  • geometry

Cite this

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title = "trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults",
abstract = "In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.",
keywords = "Pd atom, cr-tolyl, crystal, geometry",
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TY - JOUR

T1 - trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults

AU - Cross, R.J.

AU - Kennedy, A.R.

AU - Muir, K.W.

PY - 1995

Y1 - 1995

N2 - In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.

AB - In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.

KW - Pd atom

KW - cr-tolyl

KW - crystal

KW - geometry

UR - http://dx.doi.org/10.1107/S0108270194009042

U2 - 10.1107/S0108270194009042

DO - 10.1107/S0108270194009042

M3 - Article

VL - 51

SP - 208

EP - 210

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

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ER -