Towards energetically viable asymmetric deprotonations: selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

Linsey Sarah Bennie; William Kerr; Michael Middleditch; Allan Watson

doi:10.1039/c0cc04939e

Towards energetically viable asymmetric deprotonations: selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

Linsey Sarah Bennie, William Kerr, Michael Middleditch, Allan Watson

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

155 Downloads (Pure)

Abstract

A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes

Original language	English
Pages (from-to)	2264-2266
Number of pages	3
Journal	Chemical Communications (London)
Volume	47
Issue number	8
DOIs	https://doi.org/10.1039/c0cc04939e
Publication status	Published - 2011

Keywords

chemical communication
chemistry
chiral magnesium bisamide

Access to Document

10.1039/c0cc04939e

Kerr C2 CC PublishedFinal published version, 637 KBLicence: Unspecified

New Magnesium-based Enantioselective Deprotonation Methods; Greener General Base Strategies and the Development of a Catalytic Protocol x ref 040625
Kerr, W. (Principal Investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/09/05 → 31/01/09
Project: Research

Cite this

@article{64045ce6498d42af9128becc02f653bf,

title = "Towards energetically viable asymmetric deprotonations: selectivity at more elevated temperatures with C2-symmetric magnesium bisamides",

abstract = "A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes",

keywords = "chemical communication, chemistry, chiral magnesium bisamide ",

author = "Bennie, \{Linsey Sarah\} and William Kerr and Michael Middleditch and Allan Watson",

year = "2011",

doi = "10.1039/c0cc04939e",

language = "English",

volume = "47",

pages = "2264--2266",

journal = "Chemical Communications (London)",

issn = "0009-241X",

publisher = "Chemical Society",

number = "8",

}

TY - JOUR

T1 - Towards energetically viable asymmetric deprotonations

T2 - selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

AU - Bennie, Linsey Sarah

AU - Kerr, William

AU - Middleditch, Michael

AU - Watson, Allan

PY - 2011

Y1 - 2011

N2 - A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes

AB - A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes

KW - chemical communication

KW - chemistry

KW - chiral magnesium bisamide

U2 - 10.1039/c0cc04939e

DO - 10.1039/c0cc04939e

M3 - Article

SN - 0009-241X

VL - 47

SP - 2264

EP - 2266

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 8

ER -

Towards energetically viable asymmetric deprotonations: selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

Abstract

Keywords

Access to Document

Fingerprint

Projects

New Magnesium-based Enantioselective Deprotonation Methods; Greener General Base Strategies and the Development of a Catalytic Protocol x ref 040625

Cite this