Towards energetically viable asymmetric deprotonations

selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

Linsey Sarah Bennie, William Kerr, Michael Middleditch, Allan Watson

Research output: Contribution to journalArticle

11 Citations (Scopus)
130 Downloads (Pure)

Abstract

A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes
Original languageEnglish
Pages (from-to)2264-2266
Number of pages3
JournalChemical Communications (London)
Volume47
Issue number8
DOIs
Publication statusPublished - 2011

Fingerprint

Deprotonation
Magnesium
Silanes
Temperature

Keywords

  • chemical communication
  • chemistry
  • chiral magnesium bisamide

Cite this

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title = "Towards energetically viable asymmetric deprotonations: selectivity at more elevated temperatures with C2-symmetric magnesium bisamides",
abstract = "A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes",
keywords = "chemical communication, chemistry, chiral magnesium bisamide",
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Towards energetically viable asymmetric deprotonations : selectivity at more elevated temperatures with C2-symmetric magnesium bisamides. / Bennie, Linsey Sarah; Kerr, William; Middleditch, Michael; Watson, Allan.

In: Chemical Communications (London), Vol. 47, No. 8, 2011, p. 2264-2266.

Research output: Contribution to journalArticle

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T1 - Towards energetically viable asymmetric deprotonations

T2 - selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

AU - Bennie, Linsey Sarah

AU - Kerr, William

AU - Middleditch, Michael

AU - Watson, Allan

PY - 2011

Y1 - 2011

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AB - A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes

KW - chemical communication

KW - chemistry

KW - chiral magnesium bisamide

U2 - 10.1039/c0cc04939e

DO - 10.1039/c0cc04939e

M3 - Article

VL - 47

SP - 2264

EP - 2266

JO - Chemical Communications (London)

JF - Chemical Communications (London)

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