Theory of SERS enhancement: general discussion

Duncan Graham, Roy Goodacre, Heike Arnolds, Jean-Francois Masson, George Schatz, Jeremy Baumberg, Dong-Ho Kim, Javier Aizpurua, William Lum, Alessandro Silvestri, Bart de Nijs, Yikai Xu, Giuliana Di Martino, Michael Natan, Sebastian Schlücker, Pieter Wuytens, Ian Bruzas, Christian Kuttner, Mike Hardy, Rohit Chikkaraddy & 22 others Natalia Martín Sabanés, Ines Delfino, Paul Dawson, Sylwester Gawinkowski, Nicolò Bontempi, Sumeet Mahajan, Stephanie Reich, Ben Hourahine, Steven Bell, Agata Królikowska, Marc Porter, Alex Keeler, Marlous Kamp, Augustus Fountain, Claudia Fasolato, Fabrizio Giorgis, Juan C Otero, Cristiano Matricardi, Richard Van Duyne, John Lombardi, Volker Deckert, Leonora Velleman

Research output: Contribution to journalComment/debate

6 Citations (Scopus)

Abstract

Rohit Chikkaraddy opened the discussion of the Introductory Lecture: Regarding quantifying the chemical enhancement, you showed a systematic change in the SERS enhancement for halide substituted molecules due to charge transfer from the metal. Is the extra enhancement due to an inherent increase in the Raman cross-section of the molecule? How do you go about referencing, as the charge transfer changes the vibrational frequency?
LanguageEnglish
Pages173-211
Number of pages39
JournalFaraday Discussions
Volume205
DOIs
Publication statusPublished - 22 Nov 2017
EventFaraday Discussion on SERS - , United Kingdom
Duration: 30 Aug 2017 → …

Fingerprint

Charge transfer
Molecules
augmentation
Vibrational spectra
charge transfer
Metals
lectures
halides
molecules
cross sections
metals

Keywords

  • surface enhanced Raman scattering
  • spectral range

Cite this

Graham, D., Goodacre, R., Arnolds, H., Masson, J-F., Schatz, G., Baumberg, J., ... Velleman, L. (2017). Theory of SERS enhancement: general discussion. Faraday Discussions, 205, 173-211. https://doi.org/10.1039/c7fd90095c
Graham, Duncan ; Goodacre, Roy ; Arnolds, Heike ; Masson, Jean-Francois ; Schatz, George ; Baumberg, Jeremy ; Kim, Dong-Ho ; Aizpurua, Javier ; Lum, William ; Silvestri, Alessandro ; de Nijs, Bart ; Xu, Yikai ; Di Martino, Giuliana ; Natan, Michael ; Schlücker, Sebastian ; Wuytens, Pieter ; Bruzas, Ian ; Kuttner, Christian ; Hardy, Mike ; Chikkaraddy, Rohit ; Martín Sabanés, Natalia ; Delfino, Ines ; Dawson, Paul ; Gawinkowski, Sylwester ; Bontempi, Nicolò ; Mahajan, Sumeet ; Reich, Stephanie ; Hourahine, Ben ; Bell, Steven ; Królikowska, Agata ; Porter, Marc ; Keeler, Alex ; Kamp, Marlous ; Fountain, Augustus ; Fasolato, Claudia ; Giorgis, Fabrizio ; Otero, Juan C ; Matricardi, Cristiano ; Van Duyne, Richard ; Lombardi, John ; Deckert, Volker ; Velleman, Leonora. / Theory of SERS enhancement : general discussion. In: Faraday Discussions. 2017 ; Vol. 205. pp. 173-211.
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Graham, D, Goodacre, R, Arnolds, H, Masson, J-F, Schatz, G, Baumberg, J, Kim, D-H, Aizpurua, J, Lum, W, Silvestri, A, de Nijs, B, Xu, Y, Di Martino, G, Natan, M, Schlücker, S, Wuytens, P, Bruzas, I, Kuttner, C, Hardy, M, Chikkaraddy, R, Martín Sabanés, N, Delfino, I, Dawson, P, Gawinkowski, S, Bontempi, N, Mahajan, S, Reich, S, Hourahine, B, Bell, S, Królikowska, A, Porter, M, Keeler, A, Kamp, M, Fountain, A, Fasolato, C, Giorgis, F, Otero, JC, Matricardi, C, Van Duyne, R, Lombardi, J, Deckert, V & Velleman, L 2017, 'Theory of SERS enhancement: general discussion' Faraday Discussions, vol. 205, pp. 173-211. https://doi.org/10.1039/c7fd90095c

Theory of SERS enhancement : general discussion. / Graham, Duncan; Goodacre, Roy; Arnolds, Heike; Masson, Jean-Francois; Schatz, George; Baumberg, Jeremy; Kim, Dong-Ho; Aizpurua, Javier; Lum, William; Silvestri, Alessandro; de Nijs, Bart; Xu, Yikai; Di Martino, Giuliana; Natan, Michael; Schlücker, Sebastian; Wuytens, Pieter; Bruzas, Ian; Kuttner, Christian; Hardy, Mike; Chikkaraddy, Rohit; Martín Sabanés, Natalia; Delfino, Ines; Dawson, Paul; Gawinkowski, Sylwester; Bontempi, Nicolò; Mahajan, Sumeet; Reich, Stephanie; Hourahine, Ben; Bell, Steven; Królikowska, Agata; Porter, Marc; Keeler, Alex; Kamp, Marlous; Fountain, Augustus; Fasolato, Claudia; Giorgis, Fabrizio; Otero, Juan C; Matricardi, Cristiano; Van Duyne, Richard; Lombardi, John; Deckert, Volker; Velleman, Leonora.

In: Faraday Discussions, Vol. 205, 22.11.2017, p. 173-211.

Research output: Contribution to journalComment/debate

TY - JOUR

T1 - Theory of SERS enhancement

T2 - Faraday Discussions

AU - Graham, Duncan

AU - Goodacre, Roy

AU - Arnolds, Heike

AU - Masson, Jean-Francois

AU - Schatz, George

AU - Baumberg, Jeremy

AU - Kim, Dong-Ho

AU - Aizpurua, Javier

AU - Lum, William

AU - Silvestri, Alessandro

AU - de Nijs, Bart

AU - Xu, Yikai

AU - Di Martino, Giuliana

AU - Natan, Michael

AU - Schlücker, Sebastian

AU - Wuytens, Pieter

AU - Bruzas, Ian

AU - Kuttner, Christian

AU - Hardy, Mike

AU - Chikkaraddy, Rohit

AU - Martín Sabanés, Natalia

AU - Delfino, Ines

AU - Dawson, Paul

AU - Gawinkowski, Sylwester

AU - Bontempi, Nicolò

AU - Mahajan, Sumeet

AU - Reich, Stephanie

AU - Hourahine, Ben

AU - Bell, Steven

AU - Królikowska, Agata

AU - Porter, Marc

AU - Keeler, Alex

AU - Kamp, Marlous

AU - Fountain, Augustus

AU - Fasolato, Claudia

AU - Giorgis, Fabrizio

AU - Otero, Juan C

AU - Matricardi, Cristiano

AU - Van Duyne, Richard

AU - Lombardi, John

AU - Deckert, Volker

AU - Velleman, Leonora

PY - 2017/11/22

Y1 - 2017/11/22

N2 - Rohit Chikkaraddy opened the discussion of the Introductory Lecture: Regarding quantifying the chemical enhancement, you showed a systematic change in the SERS enhancement for halide substituted molecules due to charge transfer from the metal. Is the extra enhancement due to an inherent increase in the Raman cross-section of the molecule? How do you go about referencing, as the charge transfer changes the vibrational frequency?

AB - Rohit Chikkaraddy opened the discussion of the Introductory Lecture: Regarding quantifying the chemical enhancement, you showed a systematic change in the SERS enhancement for halide substituted molecules due to charge transfer from the metal. Is the extra enhancement due to an inherent increase in the Raman cross-section of the molecule? How do you go about referencing, as the charge transfer changes the vibrational frequency?

KW - surface enhanced Raman scattering

KW - spectral range

U2 - 10.1039/c7fd90095c

DO - 10.1039/c7fd90095c

M3 - Comment/debate

VL - 205

SP - 173

EP - 211

JO - Faraday Discussions

JF - Faraday Discussions

SN - 1359-6640

ER -

Graham D, Goodacre R, Arnolds H, Masson J-F, Schatz G, Baumberg J et al. Theory of SERS enhancement: general discussion. Faraday Discussions. 2017 Nov 22;205:173-211. https://doi.org/10.1039/c7fd90095c