The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

A.A. McConnell; D.H. Brown; W.E. Smith

doi:10.1016/0584-8539(82)80206-7

The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

A.A. McConnell, D.H. Brown, W.E. Smith

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Abstract

Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.

Original language	English
Pages (from-to)	265-270
Number of pages	5
Journal	Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Volume	38
Issue number	2
DOIs	https://doi.org/10.1016/0584-8539(82)80206-7
Publication status	Published - 1982

Keywords

gold(III)
chloride
bipyridyl
1
10-phenanthroline
nitrogen
compounds
polymers

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10.1016/0584-8539(82)80206-7

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title = "The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline",

abstract = "Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.",

keywords = "gold(III), chloride, bipyridyl, 1, 10-phenanthroline, nitrogen, compounds, polymers",

author = "A.A. McConnell and D.H. Brown and W.E. Smith",

year = "1982",

doi = "10.1016/0584-8539(82)80206-7",

language = "English",

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pages = "265--270",

journal = "Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy",

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T1 - The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

AU - McConnell, A.A.

AU - Brown, D.H.

AU - Smith, W.E.

PY - 1982

Y1 - 1982

N2 - Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.

AB - Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.

KW - gold(III)

KW - chloride

KW - bipyridyl

KW - 1

KW - 10-phenanthroline

KW - nitrogen

KW - compounds

KW - polymers

UR - http://dx.doi.org/10.1016/0584-8539(82)80206-7

U2 - 10.1016/0584-8539(82)80206-7

DO - 10.1016/0584-8539(82)80206-7

M3 - Article

SN - 1386-1425

VL - 38

SP - 265

EP - 270

JO - Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy

IS - 2

ER -

The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

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