The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.
LanguageEnglish
Pages265-270
Number of pages5
JournalSpectrochimica acta. Part A: Molecular spectroscopy
Volume38
Issue number2
DOIs
Publication statusPublished - 1982

Fingerprint

Stretching
Gold
Ligands
Metal halides
Nitrogen
Ions
Polymers

Keywords

  • gold(III)
  • chloride
  • bipyridyl
  • 1
  • 10-phenanthroline
  • nitrogen
  • compounds
  • polymers

Cite this

@article{6490b36081ff479c9d3828b7bc4fbedb,
title = "The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline",
abstract = "Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.",
keywords = "gold(III), chloride, bipyridyl, 1, 10-phenanthroline, nitrogen, compounds, polymers",
author = "A.A. McConnell and D.H. Brown and W.E. Smith",
year = "1982",
doi = "10.1016/0584-8539(82)80206-7",
language = "English",
volume = "38",
pages = "265--270",
journal = "Spectrochimica acta. Part A: Molecular spectroscopy",
issn = "0584-8539",
publisher = "Pergamon Press Ltd.",
number = "2",

}

TY - JOUR

T1 - The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

AU - McConnell, A.A.

AU - Brown, D.H.

AU - Smith, W.E.

PY - 1982

Y1 - 1982

N2 - Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.

AB - Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.

KW - gold(III)

KW - chloride

KW - bipyridyl

KW - 1

KW - 10-phenanthroline

KW - nitrogen

KW - compounds

KW - polymers

UR - http://dx.doi.org/10.1016/0584-8539(82)80206-7

U2 - 10.1016/0584-8539(82)80206-7

DO - 10.1016/0584-8539(82)80206-7

M3 - Article

VL - 38

SP - 265

EP - 270

JO - Spectrochimica acta. Part A: Molecular spectroscopy

T2 - Spectrochimica acta. Part A: Molecular spectroscopy

JF - Spectrochimica acta. Part A: Molecular spectroscopy

SN - 0584-8539

IS - 2

ER -