The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

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Abstract

Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.
Original languageEnglish
Pages (from-to)265-270
Number of pages5
JournalSpectrochimica acta. Part A: Molecular spectroscopy
Volume38
Issue number2
DOIs
Publication statusPublished - 1982

Keywords

  • gold(III)
  • chloride
  • bipyridyl
  • 1
  • 10-phenanthroline
  • nitrogen
  • compounds
  • polymers

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