The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

A.A. McConnell, D.H. Brown, W.E. Smith

Research output: Contribution to journal › Article

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Abstract

Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.
LanguageEnglish
Pages265-270
Number of pages5
JournalSpectrochimica acta. Part A: Molecular spectroscopy
Volume38
Issue number2
DOIs
Publication statusPublished - 1982

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Stretching
Gold
Ligands
Metal halides
Nitrogen
Ions
Polymers

Keywords

  • gold(III)
  • chloride
  • bipyridyl
  • 1
  • 10-phenanthroline
  • nitrogen
  • compounds
  • polymers

Cite this

McConnell, A.A. ; Brown, D.H. ; Smith, W.E. / The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline. In: Spectrochimica acta. Part A: Molecular spectroscopy. 1982 ; Vol. 38, No. 2. pp. 265-270.
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abstract = "Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.",
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McConnell, AA, Brown, DH & Smith, WE 1982, 'The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline' Spectrochimica acta. Part A: Molecular spectroscopy, vol. 38, no. 2, pp. 265-270. https://doi.org/10.1016/0584-8539(82)80206-7

The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline. / McConnell, A.A.; Brown, D.H.; Smith, W.E.

In: Spectrochimica acta. Part A: Molecular spectroscopy, Vol. 38, No. 2, 1982, p. 265-270.

Research output: Contribution to journal › Article

TY - JOUR

T1 - The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

AU - McConnell, A.A.

AU - Brown, D.H.

AU - Smith, W.E.

PY - 1982

Y1 - 1982

N2 - Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.

AB - Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.

KW - gold(III)

KW - chloride

KW - bipyridyl

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KW - 10-phenanthroline

KW - nitrogen

KW - compounds

KW - polymers

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McConnell AA, Brown DH, Smith WE. The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline. Spectrochimica acta. Part A: Molecular spectroscopy. 1982;38(2):265-270. https://doi.org/10.1016/0584-8539(82)80206-7

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