The use of a bis(phenylpyrazolyl)pyridyl ligand to prepare [Mn4] and [Mn10] cage complexes

José Sánchez Costa; Gavin A. Craig; Leoní A. Barrios; Olivier Roubeau; Eliseo Ruiz; Silvia Gómez-Coca; Simon J. Teat; Guillem Aromí

doi:10.1002/chem.201003329

The use of a bis(phenylpyrazolyl)pyridyl ligand to prepare [Mn₄] and [Mn₁₀] cage complexes

José Sánchez Costa, Gavin A. Craig, Leoní A. Barrios, Olivier Roubeau, Eliseo Ruiz, Silvia Gómez-Coca, Simon J. Teat, Guillem Aromí

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Rational design versus serendipity: The first two high-nuclearity MnII/III clusters with a novel extended bis(phenylpyrazolyl)pyridyl ligand (see graphic) are described in a promising route for the preparation of new magnetic coordination aggregates, differing from conventional methods involving small bridging ligands.

Original language	English
Pages (from-to)	4960-4963
Number of pages	4
Journal	Chemistry - A European Journal
Volume	17
Issue number	18
Early online date	25 Mar 2011
DOIs	https://doi.org/10.1002/chem.201003329
Publication status	Published - 26 Apr 2011

Keywords

coordination chemistry
clusters compounds
ligand design
magnetic properties
manganese

Access to Document

10.1002/chem.201003329

Cite this

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abstract = "Rational design versus serendipity: The first two high-nuclearity MnII/III clusters with a novel extended bis(phenylpyrazolyl)pyridyl ligand (see graphic) are described in a promising route for the preparation of new magnetic coordination aggregates, differing from conventional methods involving small bridging ligands.",

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AU - Craig, Gavin A.

AU - Barrios, Leoní A.

AU - Roubeau, Olivier

AU - Ruiz, Eliseo

AU - Gómez-Coca, Silvia

AU - Teat, Simon J.

AU - Aromí, Guillem

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AB - Rational design versus serendipity: The first two high-nuclearity MnII/III clusters with a novel extended bis(phenylpyrazolyl)pyridyl ligand (see graphic) are described in a promising route for the preparation of new magnetic coordination aggregates, differing from conventional methods involving small bridging ligands.

KW - coordination chemistry

KW - clusters compounds

KW - ligand design

KW - magnetic properties

KW - manganese

U2 - 10.1002/chem.201003329

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