The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

D  BARR; W  CLEGG; Robert Mulvey; R  SNAITH

doi:10.1039/C39840000700

The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

D BARR, W CLEGG, Robert Mulvey, R SNAITH

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

An X-ray crystallographic study of the title compound, (1), shows it to consist of two structural isomers, one, (1A), with a planar (LiN)2 ring structure provided by µ-amido ligands, but the other,(1B), with an (LiO)2 ring due to previously unobserved bridging by the oxygen of formally neutral ligand.

Original language	English
Pages (from-to)	700-701
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39840000700
Publication status	Published - 1984

Keywords

neutral bridging oxygen ligands
oxygen ligands
structural isomers

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10.1039/C39840000700

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title = "The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands",

abstract = "An X-ray crystallographic study of the title compound, (1), shows it to consist of two structural isomers, one, (1A), with a planar (LiN)2 ring structure provided by µ-amido ligands, but the other,(1B), with an (LiO)2 ring due to previously unobserved bridging by the oxygen of formally neutral ligand.",

keywords = "neutral bridging oxygen ligands , oxygen ligands , structural isomers",

author = "D BARR and W CLEGG and Robert Mulvey and R SNAITH",

year = "1984",

doi = "10.1039/C39840000700",

language = "English",

pages = "700--701",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "11",

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The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands. / BARR, D ; CLEGG, W ; Mulvey, Robert et al.

In: Journal of the Chemical Society, Chemical Communications, No. 11, 1984, p. 700-701.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

AU - BARR, D

AU - CLEGG, W

AU - Mulvey, Robert

AU - SNAITH, R

PY - 1984

Y1 - 1984

N2 - An X-ray crystallographic study of the title compound, (1), shows it to consist of two structural isomers, one, (1A), with a planar (LiN)2 ring structure provided by µ-amido ligands, but the other,(1B), with an (LiO)2 ring due to previously unobserved bridging by the oxygen of formally neutral ligand.

AB - An X-ray crystallographic study of the title compound, (1), shows it to consist of two structural isomers, one, (1A), with a planar (LiN)2 ring structure provided by µ-amido ligands, but the other,(1B), with an (LiO)2 ring due to previously unobserved bridging by the oxygen of formally neutral ligand.

KW - neutral bridging oxygen ligands

KW - oxygen ligands

KW - structural isomers

U2 - 10.1039/C39840000700

DO - 10.1039/C39840000700

M3 - Article

SP - 700

EP - 701

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

IS - 11

ER -

The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

Abstract

Keywords

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