The potential of plasma-derived hard carbon for sodium-ion batteries

Abdul Wasy Zia, Shahid Rasul, Muhammad Asim, Yarjan Abdul Samad, Rana Abdul Shakoor, Tariq Masood

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)
133 Downloads (Pure)

Abstract

Sodium-ion batteries (SIB) are receiving wider attention due to sodium abundance and lower cost. The application of hard carbon to SIB electrodes has shown their significant potential to increase rates, capacities, stability, and overall performance. This article describes the significance of hard carbon, its structural models, and mechanisms for SIB applications. Further, this work unveils the potential of plasma methods as a scalable and sustainable manufacturing source of hard carbon to meet its increasing industrial demands for energy storage applications. The working mechanisms of major plasma technologies, the influence of their parameters on carbon structure, and their suitability for SIB applications are described. This work summarises the performance of emerging plasma-driven hard carbon solutions for SIB, including extreme environments, and revolves around the flexibilities offered by plasma methods in a wider spectrum such as multi-materials doping, in-situ multilayer fabrication, and a broad range of formulations and environments to deposit hard carbon-based electrodes for superior SIB performance. It is conceived the challenges around the stable interface, capacity fading, and uplifting SIB capacities and rates at higher voltage are currently being researched, Whereas, the development of real-time monitoring and robust diagnostic tools for SIB are new horizons. This work proposes a data-driven framework for plasma-driven hard carbon to make high-performance energy storage batteries.
Original languageEnglish
Article number110844
Number of pages14
JournalJournal of Energy Storage
Volume84
Issue numberPart B
Early online date17 Feb 2024
DOIs
Publication statusPublished - 20 Apr 2024

Funding

New and innovative energy storage solutions are evolving with NetZero global drive. Sodium-ion batteries (SIB) are receiving widespread popularity and being considered as a successor to lithium-ion batteries (LIB). Sodium (Na) has an ionic radius of 1.02 A o , is quite an abundant element with a concentration of 23,000 ppm, and has a carbonate cost of ∼ £160 per tonne [ 1 ]. Whereas, the ion size, abundance, and carbonate cost of lithium (Li) are 0.76 A o , 20 ppm, and £4750 per tonne, respectively [ 2 ]. Academically, the number of scientific publications on carbon materials for SIB has reached beyond 1000 per year in recent years [ 3 ] along with their industrial embrace. SIB usually holds lower energy storage capacities than LIB, hence it struggled for more than two decades [ 4 ] with original equipment manufacturer (OEM) and suppliers for its commercialization. However, their applications are now expanding beyond stationary energy storage units, particularly for five-passenger mid-range (257–450 km) electrical vehicles [ 1 ]. Capital research investments like the 2023 seed funding call of the Ayrton Challenge on Energy Storage (part of £1 billion Ayrton Fund by the UK Government) and, the NEXGENNA project funded by The Faraday institution, UK, are specifically boosting hard carbon research for SIB.

Keywords

  • digital twin
  • net zero
  • digital manufacturing
  • energy storage
  • plasma
  • hard carbon
  • sodium-ion batteries

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