Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 127-129 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 15 Jan 1986 |
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Keywords
- arene-soluble alkali
- tetrafluoroborate complex
Cite this
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The isolation of a highly arene-soluble alkali metal tetrafluoroborate complex, LiBF4·4HMPA [HMPA = OP(NMe2)3]: evidence for strong Li F interactions in solution. / BARR, D ; HUTTON, K B ; MORRIS, J H ; Mulvey, Robert; REED, D ; SNAITH, R .
In: Journal of the Chemical Society, Chemical Communications, No. 2, 15.01.1986, p. 127-129.Research output: Contribution to journal › Article
TY - JOUR
T1 - The isolation of a highly arene-soluble alkali metal tetrafluoroborate complex, LiBF4·4HMPA [HMPA = OP(NMe2)3]: evidence for strong Li F interactions in solution
AU - BARR, D
AU - HUTTON, K B
AU - MORRIS, J H
AU - Mulvey, Robert
AU - REED, D
AU - SNAITH, R
PY - 1986/1/15
Y1 - 1986/1/15
N2 - Reaction of BF3·OEt2 with 3 (BunLi·HMPA)[HMPA = OP(NMe2)3] has been monitored by variable-temperature 7Li and 11B n.m.r. spectroscopy and shown to produce a highly arene-soluble, crystalline complex, LiBF4·4HMPA, (1); spectroscopic, cryoscopic, and conductimetric measurements indicate that this exists in solution as tight lithium and tetrafluoroborate components held by Li F interactions.
AB - Reaction of BF3·OEt2 with 3 (BunLi·HMPA)[HMPA = OP(NMe2)3] has been monitored by variable-temperature 7Li and 11B n.m.r. spectroscopy and shown to produce a highly arene-soluble, crystalline complex, LiBF4·4HMPA, (1); spectroscopic, cryoscopic, and conductimetric measurements indicate that this exists in solution as tight lithium and tetrafluoroborate components held by Li F interactions.
KW - arene-soluble alkali
KW - tetrafluoroborate complex
U2 - 10.1039/C39860000127
DO - 10.1039/C39860000127
M3 - Article
SP - 127
EP - 129
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 2
ER -