The decomposition of electrochemically loaded palladium hydride: a thermal analysis study

L.E.A. Berlouis; P.J. Hall; A.J. Mackinnon; Alastair Wark; D. Manuelli; V. Gervais; J.E. Robertson

doi:10.1016/S0925-8388(96)02883-6

The decomposition of electrochemically loaded palladium hydride: a thermal analysis study

L.E.A. Berlouis, P.J. Hall, A.J. Mackinnon, Alastair Wark, D. Manuelli, V. Gervais, J.E. Robertson

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Abstract

Palladium samples electrochemically loaded with hydrogen have been examined in terms of their desorption characteristics using the thermal analysis methods of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The temperature of maximum desorption is shown to depend on the H:Pd ratio n when loading was carried out at current densities iD≤2 mA cm−2. The molar desorption enthalpy ΔHM, derived from the DSC and TGA data as a function of n (0.48-0.9), was found to be in good agreement with literature values at lower n but deviated at higher n.

Original language	English
Pages (from-to)	207-209
Number of pages	2
Journal	Journal of Alloys and Compounds
Volume	253-254
DOIs	https://doi.org/10.1016/S0925-8388(96)02883-6
Publication status	Published - 20 May 1997

Keywords

palladium
electrochemical loading
thermal desorption

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10.1016/S0925-8388(96)02883-6

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abstract = "Palladium samples electrochemically loaded with hydrogen have been examined in terms of their desorption characteristics using the thermal analysis methods of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The temperature of maximum desorption is shown to depend on the H:Pd ratio n when loading was carried out at current densities iD≤2 mA cm−2. The molar desorption enthalpy ΔHM, derived from the DSC and TGA data as a function of n (0.48-0.9), was found to be in good agreement with literature values at lower n but deviated at higher n.",

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author = "L.E.A. Berlouis and P.J. Hall and A.J. Mackinnon and Alastair Wark and D. Manuelli and V. Gervais and J.E. Robertson",

year = "1997",

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doi = "10.1016/S0925-8388(96)02883-6",

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TY - JOUR

T1 - The decomposition of electrochemically loaded palladium hydride

T2 - a thermal analysis study

AU - Berlouis, L.E.A.

AU - Hall, P.J.

AU - Mackinnon, A.J.

AU - Wark, Alastair

AU - Manuelli, D.

AU - Gervais, V.

AU - Robertson, J.E.

PY - 1997/5/20

Y1 - 1997/5/20

N2 - Palladium samples electrochemically loaded with hydrogen have been examined in terms of their desorption characteristics using the thermal analysis methods of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The temperature of maximum desorption is shown to depend on the H:Pd ratio n when loading was carried out at current densities iD≤2 mA cm−2. The molar desorption enthalpy ΔHM, derived from the DSC and TGA data as a function of n (0.48-0.9), was found to be in good agreement with literature values at lower n but deviated at higher n.

AB - Palladium samples electrochemically loaded with hydrogen have been examined in terms of their desorption characteristics using the thermal analysis methods of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The temperature of maximum desorption is shown to depend on the H:Pd ratio n when loading was carried out at current densities iD≤2 mA cm−2. The molar desorption enthalpy ΔHM, derived from the DSC and TGA data as a function of n (0.48-0.9), was found to be in good agreement with literature values at lower n but deviated at higher n.

KW - palladium

KW - electrochemical loading

KW - thermal desorption

UR - http://dx.doi.org/10.1016/S0925-8388(96)02883-6

U2 - 10.1016/S0925-8388(96)02883-6

DO - 10.1016/S0925-8388(96)02883-6

M3 - Article

SN - 0925-8388

VL - 253-254

SP - 207

EP - 209

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

The decomposition of electrochemically loaded palladium hydride: a thermal analysis study

Abstract

Keywords

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