The cobalt(II) salt of the azo dye Orange G

Alan R. Kennedy, Scott C. McKellar, Maurice O. Okoth

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Abstract

Crystallizing the cobalt(II) salt of the azo dye Orange G from water was found to give the solvent-separated ion-pair species hexaaquacobalt(II) 7-oxo-8-(2-phenylhydrazin-1-ylidene)-7,8-dihydronaphthalene-1,3-disulfonate tetrahydrate, [Co(H2O)(6)](C16H10N2O7S2)center dot 4H(2)O. The asymmetric unit of the cobalt(II) salt contains three independent octahedral [Co(OH2)(6)](2+) cations, three azo anions, all with similar configurations, and 12 uncoordinated water molecules. The structure is closely related to that of one of the known magnesium analogues. Both structures have Z' = 3, feature nearly planar azo anions [maximum displacement of azo-N atoms from the plane of the phenyl ring = 0.058 (7) angstrom] in their hydrazone tautomeric form, form layer structures with hydrophilic and hydrophobic layers alternating along the b-axis direction, and are stabilized by an extensive network of hydrogen bonds.

Original languageEnglish
Pages (from-to)m1330-m1331
Number of pages23
JournalActa Crystallographica Section E: Structure Reports
Volume66
DOIs
Publication statusPublished - Oct 2010

Keywords

  • sulfonated monoazo dyes
  • motifs
  • cobalt salt

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