Tetrathiafulvalene-annulated dipyrrolylquinoxaline: the effect of fluoride on its optical and electrochemical behaviors

Hong-Peng Jia, John C. Forgie, Shi-Xia Liu, Lionel Sanguinet, Eric Levillain, Franck Le Derf, Marc Salle, Antonia Neels, Peter J. Skabara, Silvio Decurtins, Peter Skabara

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

A tetrathiafulvalene donor has been annulated to 2,3-di(1H-2-pyrrolyl)quinoxaline affording a new chemosensor 1, which shows a unique optical selectivity and reactivity for the fluoride ion over other anions in CH2Cl2 leading to a colorimetric response. Electrochemical polymerization of 1 occurred in the presence of fluoride. 

Original languageEnglish
Pages (from-to)1590-1594
Number of pages5
JournalTetrahedron
Volume68
Issue number5
DOIs
Publication statusPublished - 4 Feb 2012

Keywords

  • dipyrrolylquinoxaline
  • fluoride
  • electrochemical behaviors
  • electrochemical polymerization

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