Abstract
The amounts of two gases simultaneously adsorbed on a solid can be measured directly or may be inferred from chromatographic retention times. Adsorption isotherms obtained by the two methods should agree within experimental error. It is desirable to have a quantitative test of the degree of agreement between experimental results made by both methods. We establish here a new adsorption function and relationship that should exist between the measured retention times and static data if both methods and the experimental results are in perfect agreement. This function gives a test of consistency between static data and retention times that has advantages over alternative methods.
Original language | English |
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Pages (from-to) | 1514-1519 |
Number of pages | 6 |
Journal | Industrial and Engineering Chemistry Research |
Volume | 39 |
Issue number | 5 |
DOIs | |
Publication status | Published - 31 Mar 2000 |
Keywords
- binary gas adsorption isotherms
- binary chromatographic retention volumes
- retention times
- methodological approach
- adsorbtion