Tandem oxidation-Wittig-Wittig sequences for the preparation of functionalised dienoates

Stuart Lang; Richard Taylor

doi:doi: 10.1016/j.tetlet.2006.05.162

Tandem oxidation-Wittig-Wittig sequences for the preparation of functionalised dienoates

Stuart Lang, Richard Taylor

Pure And Applied Chemistry

Research output: Contribution to journal › Letter › peer-review

13 Citations (Scopus)

Abstract

A range of functionalised dienes and trienes have been prepared by one-pot processes in which alcohol oxidation is accompanied by in situ Wittig homologation using Trippett's reagent [(triphenylphosphoranylidene)acetaldehyde] followed by addition of a second stabilised phosphorane. This procedure has been applied to alpha-hydroxy carbonyl compounds and activated benzylic alcohols.

Original language	English
Pages (from-to)	5489-5492
Number of pages	4
Journal	Tetrahedron Letters
Volume	47
Issue number	31
DOIs	https://doi.org/doi: 10.1016/j.tetlet.2006.05.162
Publication status	Published - 31 Jul 2006

Keywords

tandem
oxidation-wittig-wittig sequences
preparation
functionalised dienoates

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doi: 10.1016/j.tetlet.2006.05.162

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title = "Tandem oxidation-Wittig-Wittig sequences for the preparation of functionalised dienoates",

abstract = "A range of functionalised dienes and trienes have been prepared by one-pot processes in which alcohol oxidation is accompanied by in situ Wittig homologation using Trippett's reagent [(triphenylphosphoranylidene)acetaldehyde] followed by addition of a second stabilised phosphorane. This procedure has been applied to alpha-hydroxy carbonyl compounds and activated benzylic alcohols.",

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author = "Stuart Lang and Richard Taylor",

year = "2006",

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T1 - Tandem oxidation-Wittig-Wittig sequences for the preparation of functionalised dienoates

AU - Lang, Stuart

AU - Taylor, Richard

PY - 2006/7/31

Y1 - 2006/7/31

N2 - A range of functionalised dienes and trienes have been prepared by one-pot processes in which alcohol oxidation is accompanied by in situ Wittig homologation using Trippett's reagent [(triphenylphosphoranylidene)acetaldehyde] followed by addition of a second stabilised phosphorane. This procedure has been applied to alpha-hydroxy carbonyl compounds and activated benzylic alcohols.

AB - A range of functionalised dienes and trienes have been prepared by one-pot processes in which alcohol oxidation is accompanied by in situ Wittig homologation using Trippett's reagent [(triphenylphosphoranylidene)acetaldehyde] followed by addition of a second stabilised phosphorane. This procedure has been applied to alpha-hydroxy carbonyl compounds and activated benzylic alcohols.

KW - tandem

KW - oxidation-wittig-wittig sequences

KW - preparation

KW - functionalised dienoates

U2 - doi: 10.1016/j.tetlet.2006.05.162

DO - doi: 10.1016/j.tetlet.2006.05.162

M3 - Letter

SN - 0040-4039

VL - 47

SP - 5489

EP - 5492

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 31

ER -

Tandem oxidation-Wittig-Wittig sequences for the preparation of functionalised dienoates

Abstract

Keywords

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