Synthetic sodalite doped with silver nanoparticles: characterization and mercury (II) removal from aqueous solutions

In this work, a novel silver nanoparticles-doped synthetic sodalitic composite was synthesized and characterized using advanced characterization methods, namely TEM-EDS, XRD, SEM, XRF, BET, zeta potential, and particle size analysis. The synthesized nanocomposite was used for the removal of Hg²⁺ from 10 ppm aqueous solutions of initial pH equal to 2. The results showed that the sodalitic nanocomposites removed up to 98.65% of Hg²⁺, which is ∼16% and 70% higher than the removal achieved by sodalite and parent coal fly ash, respectively. The findings revealed that the Hg²⁺ removal mechanism is a multifaceted mechanism that predominantly involves adsorption, precipitation and Hg-Ag amalgamation. The study of the anions effect (Cl⁻, NO₃⁻, C₂H₃O₂⁻, and SO₄²⁻) indicated that the Hg²⁺ uptake is comparatively higher when Cl⁻ anions co-exist with Hg²⁺ in the solution.