Synthetic and structural studies of mixed sodium bis(trimethylsilyl)amide/sodium halide aggregates in the presence of η2-N,N-, η3-N,N,N/N,O,N-, and η4-N,N,N,N-donor ligands

Ana I. Ojeda-Amador, Antonio J. Martinez-Martinez, Alan R. Kennedy, Charles T. O'Hara

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Abstract

When the important utility amide sodium bis(trimethylsilyl)amide is combined with hydrocarbon-soluble molecular forms of sodium halide salts, a complex structural chemistry is observed. Through utilization of several different multidentate donor molecules, it is possible to isolate a series of compounds that have structural motifs previously not observed in sodium chemistry.
Original languageEnglish
Pages (from-to)9833-9844
Number of pages11
JournalInorganic Chemistry
Volume54
Issue number20
Early online date29 Sep 2015
DOIs
Publication statusPublished - 19 Oct 2015

Keywords

  • n-hexane solutions
  • cesium halide
  • amide/sodium halide complex
  • alkali-metal halide salts

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