Synthetic and structural studies of mixed sodium bis(trimethylsilyl)amide/sodium halide aggregates in the presence of η2-N,N-, η3-N,N,N/N,O,N-, and η4-N,N,N,N-donor ligands

Ana I. Ojeda-Amador, Antonio J. Martinez-Martinez, Alan R. Kennedy, Charles T. O'Hara

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

When the important utility amide sodium bis(trimethylsilyl)amide is combined with hydrocarbon-soluble molecular forms of sodium halide salts, a complex structural chemistry is observed. Through utilization of several different multidentate donor molecules, it is possible to isolate a series of compounds that have structural motifs previously not observed in sodium chemistry.
LanguageEnglish
Pages9833-9844
Number of pages11
JournalInorganic Chemistry
Volume54
Issue number20
Early online date29 Sep 2015
DOIs
Publication statusPublished - 19 Oct 2015

Fingerprint

Amides
amides
halides
Sodium
sodium
Ligands
ligands
chemistry
Hydrocarbons
Salts
hydrocarbons
salts
Molecules
molecules

Keywords

  • n-hexane solutions
  • cesium halide
  • amide/sodium halide complex
  • alkali-metal halide salts

Cite this

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title = "Synthetic and structural studies of mixed sodium bis(trimethylsilyl)amide/sodium halide aggregates in the presence of η2-N,N-, η3-N,N,N/N,O,N-, and η4-N,N,N,N-donor ligands",
abstract = "When the important utility amide sodium bis(trimethylsilyl)amide is combined with hydrocarbon-soluble molecular forms of sodium halide salts, a complex structural chemistry is observed. Through utilization of several different multidentate donor molecules, it is possible to isolate a series of compounds that have structural motifs previously not observed in sodium chemistry.",
keywords = "n-hexane solutions, cesium halide, amide/sodium halide complex, alkali-metal halide salts",
author = "Ojeda-Amador, {Ana I.} and Martinez-Martinez, {Antonio J.} and Kennedy, {Alan R.} and O'Hara, {Charles T.}",
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journal = "Inorganic Chemistry",
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T1 - Synthetic and structural studies of mixed sodium bis(trimethylsilyl)amide/sodium halide aggregates in the presence of η2-N,N-, η3-N,N,N/N,O,N-, and η4-N,N,N,N-donor ligands

AU - Ojeda-Amador, Ana I.

AU - Martinez-Martinez, Antonio J.

AU - Kennedy, Alan R.

AU - O'Hara, Charles T.

PY - 2015/10/19

Y1 - 2015/10/19

N2 - When the important utility amide sodium bis(trimethylsilyl)amide is combined with hydrocarbon-soluble molecular forms of sodium halide salts, a complex structural chemistry is observed. Through utilization of several different multidentate donor molecules, it is possible to isolate a series of compounds that have structural motifs previously not observed in sodium chemistry.

AB - When the important utility amide sodium bis(trimethylsilyl)amide is combined with hydrocarbon-soluble molecular forms of sodium halide salts, a complex structural chemistry is observed. Through utilization of several different multidentate donor molecules, it is possible to isolate a series of compounds that have structural motifs previously not observed in sodium chemistry.

KW - n-hexane solutions

KW - cesium halide

KW - amide/sodium halide complex

KW - alkali-metal halide salts

U2 - 10.1021/acs.inorgchem.5b01584

DO - 10.1021/acs.inorgchem.5b01584

M3 - Article

VL - 54

SP - 9833

EP - 9844

JO - Inorganic Chemistry

T2 - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 20

ER -