Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity

G.C. Forbes, F.R. Kenley, A.R. Kennedy, R.E. Mulvey, C.T. O'Hara, J.A. Parkinson

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its "guest" anion is intramolecularly stitched into the complex fused-ring structure of its cationic "host".
LanguageEnglish
Pages1140-1141
Number of pages1
JournalChemical Communications (London)
Volume2003
Issue number10
DOIs
Publication statusPublished - 17 Apr 2003

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Lithium
Amides
Magnesium
Anions
Potassium
Molecules

Keywords

  • inverse crown family
  • heterobimetallic
  • cationic rings surrounding anionic cores
  • heterotrimetallic
  • guest anion
  • intramolecularly
  • cationic

Cite this

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title = "Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity",
abstract = "Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its {"}guest{"} anion is intramolecularly stitched into the complex fused-ring structure of its cationic {"}host{"}.",
keywords = "inverse crown family, heterobimetallic, cationic rings surrounding anionic cores, heterotrimetallic, guest anion, intramolecularly, cationic",
author = "G.C. Forbes and F.R. Kenley and A.R. Kennedy and R.E. Mulvey and C.T. O'Hara and J.A. Parkinson",
year = "2003",
month = "4",
day = "17",
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language = "English",
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pages = "1140--1141",
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TY - JOUR

T1 - Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4{But(Me3Si)N}4{But[Me2(H2C)Si]N}4]: an inverse crown molecule with an atomless cavity

AU - Forbes, G.C.

AU - Kenley, F.R.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

AU - O'Hara, C.T.

AU - Parkinson, J.A.

PY - 2003/4/17

Y1 - 2003/4/17

N2 - Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its "guest" anion is intramolecularly stitched into the complex fused-ring structure of its cationic "host".

AB - Unlike previous members of the inverse crown family, which are heterobimetallic and have cationic rings surrounding anionic cores, the title compound is heterotrimetallic and its "guest" anion is intramolecularly stitched into the complex fused-ring structure of its cationic "host".

KW - inverse crown family

KW - heterobimetallic

KW - cationic rings surrounding anionic cores

KW - heterotrimetallic

KW - guest anion

KW - intramolecularly

KW - cationic

UR - http://dx.doi.org/ 10.1039/b301374j

U2 - 10.1039/b301374j

DO - 10.1039/b301374j

M3 - Article

VL - 2003

SP - 1140

EP - 1141

JO - Chemical Communications (London)

T2 - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

IS - 10

ER -