Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres

A.R. Kennedy, J.G. MacLellan, J.H. Moir, R.E. Mulvey, P.J.A. Rodger

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Reaction of the magnesium amide Mg(TMP)2 with the lithium amide LiHMDS is accompanied by an unexpected, sterically-promoted hydrogen transfer/amine elimination process, to yield the novel title compound which is the first such heterometallic composition to contain a heteroleptic amide ligand set.
LanguageEnglish
Pages1757-1758
Number of pages1
JournalChemical Communications (London)
Volume2000
Issue number18
DOIs
Publication statusPublished - 2 Aug 2000

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Thymidine Monophosphate
Lithium
Amides
Magnesium
Nitrogen
Amines
Hydrogen
Ligands
Chemical analysis

Keywords

  • magnesium amide Mg(TMP)2
  • lithium amide LiHMDS
  • heterometallic composition
  • heteroleptic

Cite this

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title = "Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres",
abstract = "Reaction of the magnesium amide Mg(TMP)2 with the lithium amide LiHMDS is accompanied by an unexpected, sterically-promoted hydrogen transfer/amine elimination process, to yield the novel title compound which is the first such heterometallic composition to contain a heteroleptic amide ligand set.",
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T1 - Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres

AU - Kennedy, A.R.

AU - MacLellan, J.G.

AU - Moir, J.H.

AU - Mulvey, R.E.

AU - Rodger, P.J.A.

PY - 2000/8/2

Y1 - 2000/8/2

N2 - Reaction of the magnesium amide Mg(TMP)2 with the lithium amide LiHMDS is accompanied by an unexpected, sterically-promoted hydrogen transfer/amine elimination process, to yield the novel title compound which is the first such heterometallic composition to contain a heteroleptic amide ligand set.

AB - Reaction of the magnesium amide Mg(TMP)2 with the lithium amide LiHMDS is accompanied by an unexpected, sterically-promoted hydrogen transfer/amine elimination process, to yield the novel title compound which is the first such heterometallic composition to contain a heteroleptic amide ligand set.

KW - magnesium amide Mg(TMP)2

KW - lithium amide LiHMDS

KW - heterometallic composition

KW - heteroleptic

UR - http://dx.doi.org/10.1039/b004317f

U2 - 10.1039/b004317f

DO - 10.1039/b004317f

M3 - Article

VL - 2000

SP - 1757

EP - 1758

JO - Chemical Communications (London)

T2 - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

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ER -