TY - JOUR
T1 - Synthesis of poly(triarylamine)s by C-N coupling catalyzed by (N-heterocyclic carbene)-palladium complexes
AU - Sprick, Reiner Sebastian
AU - Hoyos, Mario
AU - Navarro, Oscar
AU - Turner, Michael Lewis
PY - 2012/5/1
Y1 - 2012/5/1
N2 - The use of (N-heterocyclic carbene)-palladium complexes as precatalysts for the synthesis of poly(triarylamine)s by C-N coupling is reported. Effective control of the molecular weight distribution by in situ end-capping during the polymerization was found to be important for application of these polymers as the charge transporting layers of OFETs.
AB - The use of (N-heterocyclic carbene)-palladium complexes as precatalysts for the synthesis of poly(triarylamine)s by C-N coupling is reported. Effective control of the molecular weight distribution by in situ end-capping during the polymerization was found to be important for application of these polymers as the charge transporting layers of OFETs.
KW - Buchwald-Hartwig amination
KW - N-heterocyclic carbene
KW - Organic field-effect transistor
KW - poly(triarylamine)
KW - semiconducting polymer
UR - http://www.scopus.com/inward/record.url?scp=84859486306&partnerID=8YFLogxK
U2 - 10.1016/j.reactfunctpolym.2012.02.008
DO - 10.1016/j.reactfunctpolym.2012.02.008
M3 - Article
AN - SCOPUS:84859486306
VL - 72
SP - 337
EP - 340
JO - Reactive and Functional Polymers
JF - Reactive and Functional Polymers
SN - 1381-5148
IS - 5
ER -