Abstract
| Language | English |
|---|---|
| Pages | 17781-17794 |
| Number of pages | 13 |
| Journal | Tetrahedron |
| Volume | 53 |
| Issue number | 52 |
| DOIs | |
| Publication status | Published - 29 Dec 1997 |
Fingerprint
Keywords
- ttf derivatives
- dimeric tetrathiafulvalenes
- building-blocks
- donors
- dimensionality
- substituents
- diffraction
- chemistry
- complexes
- metals
Cite this
}
Synthesis of new mono-functionalised tetrathiafulvalene derivatives by reactions of tetrathiafulvalenyllithium with aldehydes and ketones: X-ray crystal structures of TTF-CMe(OH)Fc, TTF-CMe(OMe)Fc and TTF-CH(OMe)TTF (Fc = ferrocenyl). / Bryce, M.R.; Skabara, P.J.; Moore, A.J.; Batsanov, A.S.; Howard, J.A.K.; Hoy, V.J.
In: Tetrahedron, Vol. 53, No. 52, 29.12.1997, p. 17781-17794.Research output: Contribution to journal › Article
TY - JOUR
T1 - Synthesis of new mono-functionalised tetrathiafulvalene derivatives by reactions of tetrathiafulvalenyllithium with aldehydes and ketones: X-ray crystal structures of TTF-CMe(OH)Fc, TTF-CMe(OMe)Fc and TTF-CH(OMe)TTF (Fc = ferrocenyl)
AU - Bryce, M.R.
AU - Skabara, P.J.
AU - Moore, A.J.
AU - Batsanov, A.S.
AU - Howard, J.A.K.
AU - Hoy, V.J.
PY - 1997/12/29
Y1 - 1997/12/29
N2 - Reactions of tetrathiafulvalenyllithium (TTF-Li) with a range of aldehydes and ketones have been explored for the first time, to provide an efficient route to mono-functionalised TTF derivatives of general formulae TTF-CH(OH)R (R = alkyl, phenyl, tetrathiafulvalenyl and ferrocenyl) and TTF-CR(OH)R' (R = alkyl, phenyl R' = alkyl, phenyl, tetrathiafulvalenyl, ferrocenyl and R-R' = fluorenyl). Subsequent transformations involving the reactive alcohol group of some of these compounds are reported. The structures of the three title compounds have been established by single-crystal X-ray analysis.
AB - Reactions of tetrathiafulvalenyllithium (TTF-Li) with a range of aldehydes and ketones have been explored for the first time, to provide an efficient route to mono-functionalised TTF derivatives of general formulae TTF-CH(OH)R (R = alkyl, phenyl, tetrathiafulvalenyl and ferrocenyl) and TTF-CR(OH)R' (R = alkyl, phenyl R' = alkyl, phenyl, tetrathiafulvalenyl, ferrocenyl and R-R' = fluorenyl). Subsequent transformations involving the reactive alcohol group of some of these compounds are reported. The structures of the three title compounds have been established by single-crystal X-ray analysis.
KW - ttf derivatives
KW - dimeric tetrathiafulvalenes
KW - building-blocks
KW - donors
KW - dimensionality
KW - substituents
KW - diffraction
KW - chemistry
KW - complexes
KW - metals
UR - http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6THR-3XBTT06-19-8&_cdi=5289&_user=875629&_orig=search&_coverDate=12%2F29%2F1997&_qd=1&_sk=999469947&view=c&wchp=dGLbVtb-zSkWA&md5=ccf950d2a35106e85f0fd6b09750bd6b&ie=/sdarticle.pdf
UR - http://dx.doi.org/10.1016/S0040-4020(97)10243-5
U2 - 10.1016/S0040-4020(97)10243-5
DO - 10.1016/S0040-4020(97)10243-5
M3 - Article
VL - 53
SP - 17781
EP - 17794
JO - Tetrahedron
T2 - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 52
ER -