Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature

Thomas W.S. Yip, E.J. Cussen, Donald MacLaren

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH.H2O at room temperature give targeted compositions in the series HxLi1-xLaTiO4. Remarkably, the Li+ and H+ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds.
LanguageEnglish
Pages698-700
Number of pages3
JournalChemical Communications (London)
Volume46
Issue number5
Early online date30 Nov 2009
DOIs
Publication statusPublished - 7 Feb 2010

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Solid state reactions
Ion exchange
Ions
Chemical analysis
Temperature
perovskite

Keywords

  • solid state reactions
  • room temperature
  • organic chemistry

Cite this

Yip, Thomas W.S. ; Cussen, E.J. ; MacLaren, Donald. / Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature. In: Chemical Communications (London). 2010 ; Vol. 46, No. 5. pp. 698-700.
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Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature. / Yip, Thomas W.S.; Cussen, E.J.; MacLaren, Donald.

In: Chemical Communications (London), Vol. 46, No. 5, 07.02.2010, p. 698-700.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature

AU - Yip, Thomas W.S.

AU - Cussen, E.J.

AU - MacLaren, Donald

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N2 - The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH.H2O at room temperature give targeted compositions in the series HxLi1-xLaTiO4. Remarkably, the Li+ and H+ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds.

AB - The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH.H2O at room temperature give targeted compositions in the series HxLi1-xLaTiO4. Remarkably, the Li+ and H+ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds.

KW - solid state reactions

KW - room temperature

KW - organic chemistry

U2 - 10.1039/B920837B

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M3 - Article

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T2 - Chemical Communications (London)

JF - Chemical Communications (London)

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