The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH.H2O at room temperature give targeted compositions in the series HxLi1-xLaTiO4. Remarkably, the Li+ and H+ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds.
- solid state reactions
- room temperature
- organic chemistry
Yip, T. W. S., Cussen, E. J., & MacLaren, D. (2010). Synthesis of HxLi1-xLaTiO4 from quantitative solid-state reactions at room temperature. Chemical Communications (London), 46(5), 698-700. https://doi.org/10.1039/B920837B