Synthesis of heteroleptic bis(amides): crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

Kenneth W. Henderson; Robert Mulvey; William Clegg; Paul A. O'Neil

doi:10.1016/S0277-5387(00)83080-6

Synthesis of heteroleptic bis(amides): crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

Kenneth W. Henderson, Robert Mulvey, William Clegg, Paul A. O'Neil

Pure And Applied Chemistry

Research output: Contribution to journal › Comment/debate

20 Citations (Scopus)

Abstract

Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

Original language	English
Pages (from-to)	2535-2538
Number of pages	4
Journal	Polyhedron
Volume	12
Issue number	20
DOIs	https://doi.org/10.1016/S0277-5387(00)83080-6
Publication status	Published - Oct 1993

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Keywords

Lithium Diisopropylamide LDA
amides
reagent

Cite this

Henderson, K. W., Mulvey, R., Clegg, W., & O'Neil, P. A. (1993). Synthesis of heteroleptic bis(amides): crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]. Polyhedron, 12(20), 2535-2538. https://doi.org/10.1016/S0277-5387(00)83080-6

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abstract = "Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.",

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T2 - crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

AU - Henderson, Kenneth W.

AU - Mulvey, Robert

AU - Clegg, William

AU - O'Neil, Paul A.

PY - 1993/10

Y1 - 1993/10

N2 - Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

AB - Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

KW - Lithium Diisopropylamide LDA

KW - amides

KW - reagent

U2 - 10.1016/S0277-5387(00)83080-6

DO - 10.1016/S0277-5387(00)83080-6

M3 - Comment/debate

VL - 12

SP - 2535

EP - 2538

JO - Polyhedron

JF - Polyhedron

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Access to Document

10.1016/S0277-5387(00)83080-6