Synthesis of heteroleptic bis(amides): crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

Kenneth W. Henderson; Robert Mulvey; William Clegg; Paul A. O'Neil

doi:10.1016/S0277-5387(00)83080-6

Synthesis of heteroleptic bis(amides): crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

Kenneth W. Henderson, Robert Mulvey, William Clegg, Paul A. O'Neil

Pure And Applied Chemistry

Research output: Contribution to journal › Comment/debate

20 Citations (Scopus)

Abstract

Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

Original language	English
Pages (from-to)	2535-2538
Number of pages	4
Journal	Polyhedron
Volume	12
Issue number	20
DOIs	https://doi.org/10.1016/S0277-5387(00)83080-6
Publication status	Published - Oct 1993

Keywords

Lithium Diisopropylamide LDA
amides
reagent

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10.1016/S0277-5387(00)83080-6

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@article{8c26ece99f8b47349a3a7b8ad2b58456,

title = "Synthesis of heteroleptic bis(amides): crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]",

abstract = "Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.",

keywords = "Lithium Diisopropylamide LDA, amides, reagent",

author = "Henderson, {Kenneth W.} and Robert Mulvey and William Clegg and O'Neil, {Paul A.}",

year = "1993",

month = oct,

doi = "10.1016/S0277-5387(00)83080-6",

language = "English",

volume = "12",

pages = "2535--2538",

journal = "Polyhedron",

issn = "0277-5387",

number = "20",

}

TY - JOUR

T1 - Synthesis of heteroleptic bis(amides)

T2 - crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

AU - Henderson, Kenneth W.

AU - Mulvey, Robert

AU - Clegg, William

AU - O'Neil, Paul A.

PY - 1993/10

Y1 - 1993/10

N2 - Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

AB - Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

KW - Lithium Diisopropylamide LDA

KW - amides

KW - reagent

U2 - 10.1016/S0277-5387(00)83080-6

DO - 10.1016/S0277-5387(00)83080-6

M3 - Comment/debate

VL - 12

SP - 2535

EP - 2538

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 20

ER -