Synthesis of heteroleptic bis(amides)

crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

Kenneth W. Henderson, Robert Mulvey, William Clegg, Paul A. O'Neil

Research output: Contribution to journal › Comment/debate

20 Citations (Scopus)

Abstract

Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

Original languageEnglish
Pages (from-to)2535-2538
Number of pages4
JournalPolyhedron
Volume12
Issue number20
DOIs
Publication statusPublished - Oct 1993

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Amides
Dimers
Magnesium
amides
Amines
Crystal structure
crystal structure
Substrates
synthesis
magnesium
amines
dimers
rings

Keywords

  • Lithium Diisopropylamide LDA
  • amides
  • reagent

Cite this

Henderson, Kenneth W. ; Mulvey, Robert ; Clegg, William ; O'Neil, Paul A. / Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]. In: Polyhedron. 1993 ; Vol. 12, No. 20. pp. 2535-2538.
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abstract = "Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.",
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author = "Henderson, {Kenneth W.} and Robert Mulvey and William Clegg and O'Neil, {Paul A.}",
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volume = "12",
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Henderson, KW, Mulvey, R, Clegg, W & O'Neil, PA 1993, 'Synthesis of heteroleptic bis(amides): crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]', Polyhedron, vol. 12, no. 20, pp. 2535-2538. https://doi.org/10.1016/S0277-5387(00)83080-6

Synthesis of heteroleptic bis(amides) : crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]. / Henderson, Kenneth W.; Mulvey, Robert; Clegg, William; O'Neil, Paul A.

In: Polyhedron, Vol. 12, No. 20, 10.1993, p. 2535-2538.

Research output: Contribution to journal › Comment/debate

TY - JOUR

T1 - Synthesis of heteroleptic bis(amides)

T2 - crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]

AU - Henderson, Kenneth W.

AU - Mulvey, Robert

AU - Clegg, William

AU - O'Neil, Paul A.

PY - 1993/10

Y1 - 1993/10

N2 - Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

AB - Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.

KW - Lithium Diisopropylamide LDA

KW - amides

KW - reagent

U2 - 10.1016/S0277-5387(00)83080-6

DO - 10.1016/S0277-5387(00)83080-6

M3 - Comment/debate

VL - 12

SP - 2535

EP - 2538

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 20

ER -

Henderson KW, Mulvey R, Clegg W, O'Neil PA. Synthesis of heteroleptic bis(amides): crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]. Polyhedron. 1993 Oct;12(20):2535-2538. https://doi.org/10.1016/S0277-5387(00)83080-6

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