TY - JOUR
T1 - Synthesis of heteroleptic bis(amides)
T2 - crystal structure of the representative compound, [{Mg[N(Ph)2][Ph)(2-Pyr)]}2]
AU - Henderson, Kenneth W.
AU - Mulvey, Robert
AU - Clegg, William
AU - O'Neil, Paul A.
PY - 1993/10
Y1 - 1993/10
N2 - Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.
AB - Reaction of Ph(2-Pyr)NH with ''Mg(Bu)2'', followed by addition of amine substrates, gives heteroleptic magnesium bis(amides), one of which, [{Mg[N(Ph)2][N(Ph)(2-Pyr)]}2], has been crystallographically characterized and shown to be a dimer with a central, rectangular azamagnesacyclic ring.
KW - Lithium Diisopropylamide LDA
KW - amides
KW - reagent
U2 - 10.1016/S0277-5387(00)83080-6
DO - 10.1016/S0277-5387(00)83080-6
M3 - Comment/debate
VL - 12
SP - 2535
EP - 2538
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 20
ER -