Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis

Liam J. Donnelly; Simon Parsons; Carole A. Morrison; Stephen P. Thomas; Jason B. Love

doi:10.1039/d0sc03458d

Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis

Liam J. Donnelly
, Simon Parsons
, Carole A. Morrison
, Stephen P. Thomas
, Jason B. Love

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

33 Downloads (Pure)

Abstract

Exhaustive deoxygenation of perrhenate by pinacol borane forms a new Re anion of boron and hydride ligands only that undergoes borane ligand exchange, stoichiometric C–H boration, and catalytic pyridine hydroboration.

Original language	English
Pages (from-to)	9994-9999
Number of pages	6
Journal	Chemical Science
Volume	11
Issue number	36
Early online date	9 Sept 2020
DOIs	https://doi.org/10.1039/d0sc03458d
Publication status	Published - 9 Sept 2020

Keywords

synthesis
structures
anionic rhenium polyhydride complexes
boron-hydride ligands
catalysis

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10.1039/d0sc03458dLicence: CC BY 4.0

Donnelly-etal-CS-2020-Synthesis-and-structures-of-anionic-rhenium-polyhydride-complexes-of-boron–hydride-ligandsFinal published version, 930 KBLicence: CC BY 4.0

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title = "Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis",

abstract = "Exhaustive deoxygenation of perrhenate by pinacol borane forms a new Re anion of boron and hydride ligands only that undergoes borane ligand exchange, stoichiometric C–H boration, and catalytic pyridine hydroboration.",

keywords = "synthesis, structures, anionic rhenium polyhydride complexes, boron-hydride ligands, catalysis",

author = "Donnelly, \{Liam J.\} and Simon Parsons and Morrison, \{Carole A.\} and Thomas, \{Stephen P.\} and Love, \{Jason B.\}",

year = "2020",

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doi = "10.1039/d0sc03458d",

language = "English",

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T1 - Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis

AU - Donnelly, Liam J.

AU - Parsons, Simon

AU - Morrison, Carole A.

AU - Thomas, Stephen P.

AU - Love, Jason B.

PY - 2020/9/9

Y1 - 2020/9/9

N2 - Exhaustive deoxygenation of perrhenate by pinacol borane forms a new Re anion of boron and hydride ligands only that undergoes borane ligand exchange, stoichiometric C–H boration, and catalytic pyridine hydroboration.

AB - Exhaustive deoxygenation of perrhenate by pinacol borane forms a new Re anion of boron and hydride ligands only that undergoes borane ligand exchange, stoichiometric C–H boration, and catalytic pyridine hydroboration.

KW - synthesis

KW - structures

KW - anionic rhenium polyhydride complexes

KW - boron-hydride ligands

KW - catalysis

U2 - 10.1039/d0sc03458d

DO - 10.1039/d0sc03458d

M3 - Article

SN - 2041-6520

VL - 11

SP - 9994

EP - 9999

JO - Chemical Science

JF - Chemical Science

IS - 36

ER -

Synthesis and structures of anionic rhenium polyhydride complexes of boron–hydride ligands and their application in catalysis

Abstract

Keywords

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