Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges

W  Clegg; A M  Drummond; Robert Mulvey; S T  Liddle

doi:10.1039/A807069E

Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges

W Clegg, A M Drummond, Robert Mulvey, S T Liddle

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.

Original language	English
Pages (from-to)	2391-2392
Number of pages	2
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/A807069E
Publication status	Published - 7 Nov 1998

Keywords

crystal structures
complexes
cations
lithium

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10.1039/A807069E

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title = "Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [\{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda\}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges",

abstract = "Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.",

keywords = "crystal structures, complexes, cations, lithium",

author = "W Clegg and Drummond, \{A M\} and Robert Mulvey and Liddle, \{S T\}",

year = "1998",

month = nov,

day = "7",

doi = "10.1039/A807069E",

language = "English",

pages = "2391--2392",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "21",

}

Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges. / Clegg, W ; Drummond, A M ; Mulvey, Robert et al.
In: Chemical Communications, No. 21, 07.11.1998, p. 2391-2392.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges

AU - Clegg, W

AU - Drummond, A M

AU - Mulvey, Robert

AU - Liddle, S T

PY - 1998/11/7

Y1 - 1998/11/7

N2 - Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.

AB - Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.

KW - crystal structures

KW - complexes

KW - cations

KW - lithium

U2 - 10.1039/A807069E

DO - 10.1039/A807069E

M3 - Article

SN - 1359-7345

SP - 2391

EP - 2392

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -