Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges

W Clegg, A M Drummond, Robert Mulvey, S T Liddle

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.

LanguageEnglish
Pages2391-2392
Number of pages2
JournalChemical Communications
Issue number21
DOIs
Publication statusPublished - 7 Nov 1998

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Rubidium
Peroxides
Lithium
Metals
Molecules
phenyllithium

Keywords

  • crystal structures
  • complexes
  • cations
  • lithium

Cite this

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title = "Synthesis and structure of the novel heptalithiumtetrarubidium mixed alkoxide peroxide [{((BuOLi)-O-t)(5)((BuORb)-O-t)(4)(Li2O2)center dot 2tmeda}(infinity)]: twenty-two vertex cage molecules linked by Rb-TMEDA-Rb bridges",
abstract = "Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.",
keywords = "crystal structures, complexes, cations, lithium",
author = "W Clegg and Drummond, {A M} and Robert Mulvey and Liddle, {S T}",
year = "1998",
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journal = "Chemical Communications",
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AU - Clegg, W

AU - Drummond, A M

AU - Mulvey, Robert

AU - Liddle, S T

PY - 1998/11/7

Y1 - 1998/11/7

N2 - Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.

AB - Made by a metal-metal partial exchange reaction involving lithium tert-butylamide, rubidium tert-butoxide and TMEDA, the title compound represents the first mixed lithium-rubidium organoelement species of its type.

KW - crystal structures

KW - complexes

KW - cations

KW - lithium

U2 - 10.1039/A807069E

DO - 10.1039/A807069E

M3 - Article

SP - 2391

EP - 2392

JO - Chemical Communications

T2 - Chemical Communications

JF - Chemical Communications

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