Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion

W.T.K. Chan, D. Eisler, F. Garcia, S. Gonzalez-Calera, M. McPartlin, J.V. Morey, R.E. Mulvey, S. Singh

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The hydrolysis of [ClP(-NtBu)]2 with H2O-Et3N in thf, followed by in situ lithiation with nBuLi gives the Li13 cage [{[OP(-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(-NtBu)]22- dianion that is isoelectronic with ligands of the type [(RN)P(-NR)]22-. (Abstract edited from: http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b800051d)
LanguageEnglish
Pages2251-2253
Number of pages2
JournalChemical Communications (London)
Issue number19
DOIs
Publication statusPublished - 21 May 2008

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Hydrolysis
Ligands

Keywords

  • RING-OPENING REACTIONS
  • CRYSTAL-STRUCTURES
  • TETRAHYDROFURAN
  • COMPLEXES
  • COORDINATION
  • MACROCYCLES
  • GUEST
  • LITHIATION
  • SELECTION
  • NITROGEN

Cite this

@article{3017c9ad1a9c4a66b90c497ecb62ff60,
title = "Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion",
abstract = "The hydrolysis of [ClP(-NtBu)]2 with H2O-Et3N in thf, followed by in situ lithiation with nBuLi gives the Li13 cage [{[OP(-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(-NtBu)]22- dianion that is isoelectronic with ligands of the type [(RN)P(-NR)]22-. (Abstract edited from: http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b800051d)",
keywords = "RING-OPENING REACTIONS, CRYSTAL-STRUCTURES, TETRAHYDROFURAN, COMPLEXES, COORDINATION, MACROCYCLES, GUEST, LITHIATION, SELECTION, NITROGEN",
author = "W.T.K. Chan and D. Eisler and F. Garcia and S. Gonzalez-Calera and M. McPartlin and J.V. Morey and R.E. Mulvey and S. Singh",
note = "Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record. http://suprimo.lib.strath.ac.uk/primo_library/libweb/action/display.do?ct=display&doc=SUVOY165400&indx=2&frbg=&dum=true&vid=SUVU01&vl(54032236UI0)=lsr02&vl(96071691UI1)=all_items&srt=rank&indx=1&dstmp=1272377732984&tab=local&ct=search&scp.scps=scope{\%}3A(SU)&vl(freeText0)=Chemical{\%}20Communications&fn=search&mode=Basic&dscnt=0",
year = "2008",
month = "5",
day = "21",
doi = "10.1039/b800051d",
language = "English",
pages = "2251--2253",
journal = "Chemical Communications (London)",
issn = "0009-241X",
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Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion. / Chan, W.T.K.; Eisler, D.; Garcia, F.; Gonzalez-Calera, S.; McPartlin, M.; Morey, J.V.; Mulvey, R.E.; Singh, S.

In: Chemical Communications (London), No. 19, 21.05.2008, p. 2251-2253.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion

AU - Chan, W.T.K.

AU - Eisler, D.

AU - Garcia, F.

AU - Gonzalez-Calera, S.

AU - McPartlin, M.

AU - Morey, J.V.

AU - Mulvey, R.E.

AU - Singh, S.

N1 - Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record. http://suprimo.lib.strath.ac.uk/primo_library/libweb/action/display.do?ct=display&doc=SUVOY165400&indx=2&frbg=&dum=true&vid=SUVU01&vl(54032236UI0)=lsr02&vl(96071691UI1)=all_items&srt=rank&indx=1&dstmp=1272377732984&tab=local&ct=search&scp.scps=scope%3A(SU)&vl(freeText0)=Chemical%20Communications&fn=search&mode=Basic&dscnt=0

PY - 2008/5/21

Y1 - 2008/5/21

N2 - The hydrolysis of [ClP(-NtBu)]2 with H2O-Et3N in thf, followed by in situ lithiation with nBuLi gives the Li13 cage [{[OP(-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(-NtBu)]22- dianion that is isoelectronic with ligands of the type [(RN)P(-NR)]22-. (Abstract edited from: http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b800051d)

AB - The hydrolysis of [ClP(-NtBu)]2 with H2O-Et3N in thf, followed by in situ lithiation with nBuLi gives the Li13 cage [{[OP(-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(-NtBu)]22- dianion that is isoelectronic with ligands of the type [(RN)P(-NR)]22-. (Abstract edited from: http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b800051d)

KW - RING-OPENING REACTIONS

KW - CRYSTAL-STRUCTURES

KW - TETRAHYDROFURAN

KW - COMPLEXES

KW - COORDINATION

KW - MACROCYCLES

KW - GUEST

KW - LITHIATION

KW - SELECTION

KW - NITROGEN

UR - http://dx.doi.org/10.1039/b800051d

U2 - 10.1039/b800051d

DO - 10.1039/b800051d

M3 - Article

SP - 2251

EP - 2253

JO - Chemical Communications (London)

T2 - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

IS - 19

ER -