Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Lisa T. Burke; Eva Hevia-Freire; Rebecca Holland; John C. Jeffery; Angela P. Leedham; Christopher A. Russell; Alexander  Steiner; Anette  Zagorski

doi:10.1039/B004192K

Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Lisa T. Burke
, Eva Hevia-Freire
, Rebecca Holland
, John C. Jeffery
, Angela P. Leedham
, Christopher A. Russell
, Alexander Steiner
, Anette Zagorski

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

Original language	English
Pages (from-to)	1769-1770
Number of pages	2
Journal	Chemical Communications (London)
Issue number	18
DOIs	https://doi.org/10.1039/B004192K
Publication status	Published - 2000

Keywords

phosphonate anion
phosphorous oxoanions
2-methoxyaniline

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title = "Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions",

abstract = "The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.",

keywords = "phosphonate anion , phosphorous oxoanions , 2-methoxyaniline ",

author = "Burke, \{Lisa T.\} and Eva Hevia-Freire and Rebecca Holland and Jeffery, \{John C.\} and Leedham, \{Angela P.\} and Russell, \{Christopher A.\} and Alexander Steiner and Anette Zagorski",

year = "2000",

doi = "10.1039/B004192K",

language = "English",

pages = "1769--1770",

journal = "Chemical Communications (London)",

issn = "0009-241X",

publisher = "Chemical Society",

number = "18",

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TY - JOUR

T1 - Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

AU - Burke, Lisa T.

AU - Hevia-Freire, Eva

AU - Holland, Rebecca

AU - Jeffery, John C.

AU - Leedham, Angela P.

AU - Russell, Christopher A.

AU - Steiner, Alexander

AU - Zagorski, Anette

PY - 2000

Y1 - 2000

N2 - The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

AB - The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

KW - phosphonate anion

KW - phosphorous oxoanions

KW - 2-methoxyaniline

U2 - 10.1039/B004192K

DO - 10.1039/B004192K

M3 - Article

SN - 0009-241X

SP - 1769

EP - 1770

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 18

ER -

Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Abstract

Keywords

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