Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Lisa T. Burke; Eva Hevia-Freire; Rebecca Holland; John C. Jeffery; Angela P. Leedham; Christopher A. Russell; Alexander  Steiner; Anette  Zagorski

doi:10.1039/B004192K

Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Lisa T. Burke, Eva Hevia-Freire, Rebecca Holland, John C. Jeffery, Angela P. Leedham, Christopher A. Russell, Alexander Steiner, Anette Zagorski

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

Original language	English
Pages (from-to)	1769-1770
Number of pages	2
Journal	Chemical Communications (London)
Issue number	18
DOIs	https://doi.org/10.1039/B004192K
Publication status	Published - 2000

Keywords

phosphonate anion
phosphorous oxoanions
2-methoxyaniline

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10.1039/B004192K

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title = "Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions",

abstract = "The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.",

keywords = "phosphonate anion , phosphorous oxoanions , 2-methoxyaniline ",

author = "Burke, {Lisa T.} and Eva Hevia-Freire and Rebecca Holland and Jeffery, {John C.} and Leedham, {Angela P.} and Russell, {Christopher A.} and Alexander Steiner and Anette Zagorski",

year = "2000",

doi = "10.1039/B004192K",

language = "English",

pages = "1769--1770",

journal = "Chemical Communications (London)",

issn = "0009-241X",

publisher = "Royal Society of Chemistry",

number = "18",

}

Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. / Burke, Lisa T.; Hevia-Freire, Eva; Holland, Rebecca; Jeffery, John C.; Leedham, Angela P.; Russell, Christopher A.; Steiner, Alexander ; Zagorski, Anette .

In: Chemical Communications (London), No. 18, 2000, p. 1769-1770.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

AU - Burke, Lisa T.

AU - Hevia-Freire, Eva

AU - Holland, Rebecca

AU - Jeffery, John C.

AU - Leedham, Angela P.

AU - Russell, Christopher A.

AU - Steiner, Alexander

AU - Zagorski, Anette

PY - 2000

Y1 - 2000

N2 - The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

AB - The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

KW - phosphonate anion

KW - phosphorous oxoanions

KW - 2-methoxyaniline

U2 - 10.1039/B004192K

DO - 10.1039/B004192K

M3 - Article

SP - 1769

EP - 1770

JO - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

IS - 18

ER -

Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Abstract

Keywords

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