Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

Lisa T. Burke, Eva Hevia-Freire, Rebecca Holland, John C. Jeffery, Angela P. Leedham, Christopher A. Russell, Alexander Steiner, Anette Zagorski

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.
LanguageEnglish
Pages1769-1770
Number of pages2
JournalChemical Communications (London)
Issue number18
DOIs
Publication statusPublished - 2000

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Organophosphonates
Anions
Phosphites

Keywords

  • phosphonate anion
  • phosphorous oxoanions
  • 2-methoxyaniline

Cite this

Burke, Lisa T. ; Hevia-Freire, Eva ; Holland, Rebecca ; Jeffery, John C. ; Leedham, Angela P. ; Russell, Christopher A. ; Steiner, Alexander ; Zagorski, Anette . / Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. In: Chemical Communications (London). 2000 ; No. 18. pp. 1769-1770.
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abstract = "The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.",
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Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. / Burke, Lisa T.; Hevia-Freire, Eva; Holland, Rebecca; Jeffery, John C.; Leedham, Angela P.; Russell, Christopher A.; Steiner, Alexander ; Zagorski, Anette .

In: Chemical Communications (London), No. 18, 2000, p. 1769-1770.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions

AU - Burke, Lisa T.

AU - Hevia-Freire, Eva

AU - Holland, Rebecca

AU - Jeffery, John C.

AU - Leedham, Angela P.

AU - Russell, Christopher A.

AU - Steiner, Alexander

AU - Zagorski, Anette

PY - 2000

Y1 - 2000

N2 - The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

AB - The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

KW - phosphonate anion

KW - phosphorous oxoanions

KW - 2-methoxyaniline

U2 - 10.1039/B004192K

DO - 10.1039/B004192K

M3 - Article

SP - 1769

EP - 1770

JO - Chemical Communications (London)

T2 - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

IS - 18

ER -