Abstract
The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.
Original language | English |
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Pages (from-to) | 1769-1770 |
Number of pages | 2 |
Journal | Chemical Communications (London) |
Issue number | 18 |
DOIs | |
Publication status | Published - 2000 |
Keywords
- phosphonate anion
- phosphorous oxoanions
- 2-methoxyaniline