Abstract
| Language | English |
|---|---|
| Pages | 1769-1770 |
| Number of pages | 2 |
| Journal | Chemical Communications (London) |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 2000 |
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Keywords
- phosphonate anion
- phosphorous oxoanions
- 2-methoxyaniline
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Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions. / Burke, Lisa T.; Hevia-Freire, Eva; Holland, Rebecca; Jeffery, John C.; Leedham, Angela P.; Russell, Christopher A.; Steiner, Alexander ; Zagorski, Anette .
In: Chemical Communications (London), No. 18, 2000, p. 1769-1770.Research output: Contribution to journal › Article
TY - JOUR
T1 - Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorous oxoanions
AU - Burke, Lisa T.
AU - Hevia-Freire, Eva
AU - Holland, Rebecca
AU - Jeffery, John C.
AU - Leedham, Angela P.
AU - Russell, Christopher A.
AU - Steiner, Alexander
AU - Zagorski, Anette
PY - 2000
Y1 - 2000
N2 - The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.
AB - The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.
KW - phosphonate anion
KW - phosphorous oxoanions
KW - 2-methoxyaniline
U2 - 10.1039/B004192K
DO - 10.1039/B004192K
M3 - Article
SP - 1769
EP - 1770
JO - Chemical Communications (London)
T2 - Chemical Communications (London)
JF - Chemical Communications (London)
SN - 0009-241X
IS - 18
ER -