Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges

Luca M. Carrella; Christoph Forster; Alan R. Kennedy; Jan Klett; Robert E. Mulvey; Eva Rentschler

doi:10.1021/om100327w

Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges

Luca M. Carrella, Christoph Forster, Alan R. Kennedy, Jan Klett, Robert E. Mulvey, Eva Rentschler

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

No Cr-Cr bonding is found in a new type of mixed-metal ate complex having two coordinatively unsaturated but sterically saturated bisamido-monoalkyl Cr(II) groups linked via an unusual near-square-planar-coordinated K atom in the moiety of the ate, while the cationic moiety is a separated iris-tmeda solvated second potassium atom.

Original language	English
Pages (from-to)	4756-4758
Number of pages	3
Journal	Organometallics
Volume	29
Issue number	21
DOIs	https://doi.org/10.1021/om100327w
Publication status	Published - 8 Nov 2010

Keywords

complexes
metalation
chromium(II)

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10.1021/om100327w

Cite this

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title = "Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges",

abstract = "No Cr-Cr bonding is found in a new type of mixed-metal ate complex having two coordinatively unsaturated but sterically saturated bisamido-monoalkyl Cr(II) groups linked via an unusual near-square-planar-coordinated K atom in the moiety of the ate, while the cationic moiety is a separated iris-tmeda solvated second potassium atom.",

keywords = "complexes, metalation, chromium(II)",

author = "Carrella, \{Luca M.\} and Christoph Forster and Kennedy, \{Alan R.\} and Jan Klett and Mulvey, \{Robert E.\} and Eva Rentschler",

year = "2010",

month = nov,

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doi = "10.1021/om100327w",

language = "English",

volume = "29",

pages = "4756--4758",

journal = "Organometallics",

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publisher = "American Chemical Society",

number = "21",

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TY - JOUR

T1 - Synthesis and structure of a potassium potassiochromate

T2 - a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges

AU - Carrella, Luca M.

AU - Forster, Christoph

AU - Kennedy, Alan R.

AU - Klett, Jan

AU - Mulvey, Robert E.

AU - Rentschler, Eva

PY - 2010/11/8

Y1 - 2010/11/8

N2 - No Cr-Cr bonding is found in a new type of mixed-metal ate complex having two coordinatively unsaturated but sterically saturated bisamido-monoalkyl Cr(II) groups linked via an unusual near-square-planar-coordinated K atom in the moiety of the ate, while the cationic moiety is a separated iris-tmeda solvated second potassium atom.

AB - No Cr-Cr bonding is found in a new type of mixed-metal ate complex having two coordinatively unsaturated but sterically saturated bisamido-monoalkyl Cr(II) groups linked via an unusual near-square-planar-coordinated K atom in the moiety of the ate, while the cationic moiety is a separated iris-tmeda solvated second potassium atom.

KW - complexes

KW - metalation

KW - chromium(II)

UR - https://www.scopus.com/pages/publications/78149320958

U2 - 10.1021/om100327w

DO - 10.1021/om100327w

M3 - Article

SN - 0276-7333

VL - 29

SP - 4756

EP - 4758

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges

Abstract

Keywords

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EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)

"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

Mixed-Metal Molecular Synergy and its Application in Inverse Crown Chemistry

x-ray diffractometer

Cite this

Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Projects

EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)

"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

Mixed-Metal Molecular Synergy and its Application in Inverse Crown Chemistry

Equipment

x-ray diffractometer

Cite this