Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges

Luca M. Carrella, Christoph Forster, Alan R. Kennedy, Jan Klett, Robert E. Mulvey, Eva Rentschler

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

No Cr-Cr bonding is found in a new type of mixed-metal ate complex having two coordinatively unsaturated but sterically saturated bisamido-monoalkyl Cr(II) groups linked via an unusual near-square-planar-coordinated K atom in the moiety of the ate, while the cationic moiety is a separated iris-tmeda solvated second potassium atom.

LanguageEnglish
Pages4756-4758
Number of pages3
JournalOrganometallics
Volume29
Issue number21
DOIs
Publication statusPublished - 8 Nov 2010

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Chromium
chromium
potassium
Potassium
Ligands
Atoms
ligands
Molecules
synthesis
Metal complexes
atoms
molecules
metals

Keywords

  • complexes
  • metalation
  • chromium(II)

Cite this

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Synthesis and structure of a potassium potassiochromate : a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges. / Carrella, Luca M.; Forster, Christoph; Kennedy, Alan R.; Klett, Jan; Mulvey, Robert E.; Rentschler, Eva.

In: Organometallics, Vol. 29, No. 21, 08.11.2010, p. 4756-4758.

Research output: Contribution to journalArticle

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AU - Forster, Christoph

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AU - Mulvey, Robert E.

AU - Rentschler, Eva

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