Synthesis and structure of a potassium potassiochromate: a bis-chromium(II) molecule held together by near-square-planar potassium-ligand bridges

Luca M. Carrella, Christoph Forster, Alan R. Kennedy, Jan Klett, Robert E. Mulvey, Eva Rentschler

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

No Cr-Cr bonding is found in a new type of mixed-metal ate complex having two coordinatively unsaturated but sterically saturated bisamido-monoalkyl Cr(II) groups linked via an unusual near-square-planar-coordinated K atom in the moiety of the ate, while the cationic moiety is a separated iris-tmeda solvated second potassium atom.

Original languageEnglish
Pages (from-to)4756-4758
Number of pages3
JournalOrganometallics
Volume29
Issue number21
DOIs
Publication statusPublished - 8 Nov 2010

Keywords

  • complexes
  • metalation
  • chromium(II)

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