Synthesis and structure of a molecular barium aminebis(phenolate) and its application as an initiator for ring-opening polymerization of cyclic esters

Matthew G. Davidson; Charles T. O'Hara; Matthew D. Jones; Callum G. Keir; Mary F. Mahon; Gabriele Kociok-Kohn

doi:10.1021/ic700583e

Synthesis and structure of a molecular barium aminebis(phenolate) and its application as an initiator for ring-opening polymerization of cyclic esters

Matthew G. Davidson, Charles T. O'Hara, Matthew D. Jones, Callum G. Keir, Mary F. Mahon, Gabriele Kociok-Kohn

Pure And Applied Chemistry

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Abstract

The synthesis and structural characterization of an unusual trinuclear barium aminebis(phenolate) complex are reported along with its application as an initiator for the ring-opening polymerization of epsilon-caprolactone and L-lactide.

Original language	English
Pages (from-to)	7686-7688
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	19
DOIs	https://doi.org/10.1021/ic700583e
Publication status	Published - 17 Sept 2007

Keywords

intermolecular chain transfer
epsilon caprolactone
lactide polymerization
organometallic compounds
organocalcium halides
calcium
magnesium
complexes
strontium
zinc

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10.1021/ic700583e

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title = "Synthesis and structure of a molecular barium aminebis(phenolate) and its application as an initiator for ring-opening polymerization of cyclic esters",

abstract = "The synthesis and structural characterization of an unusual trinuclear barium aminebis(phenolate) complex are reported along with its application as an initiator for the ring-opening polymerization of epsilon-caprolactone and L-lactide.",

keywords = "intermolecular chain transfer, epsilon caprolactone, lactide polymerization, organometallic compounds, organocalcium halides, calcium, magnesium, complexes, strontium, zinc",

author = "Davidson, \{Matthew G.\} and O'Hara, \{Charles T.\} and Jones, \{Matthew D.\} and Keir, \{Callum G.\} and Mahon, \{Mary F.\} and Gabriele Kociok-Kohn",

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T1 - Synthesis and structure of a molecular barium aminebis(phenolate) and its application as an initiator for ring-opening polymerization of cyclic esters

AU - Davidson, Matthew G.

AU - O'Hara, Charles T.

AU - Jones, Matthew D.

AU - Keir, Callum G.

AU - Mahon, Mary F.

AU - Kociok-Kohn, Gabriele

PY - 2007/9/17

Y1 - 2007/9/17

N2 - The synthesis and structural characterization of an unusual trinuclear barium aminebis(phenolate) complex are reported along with its application as an initiator for the ring-opening polymerization of epsilon-caprolactone and L-lactide.

AB - The synthesis and structural characterization of an unusual trinuclear barium aminebis(phenolate) complex are reported along with its application as an initiator for the ring-opening polymerization of epsilon-caprolactone and L-lactide.

KW - intermolecular chain transfer

KW - epsilon caprolactone

KW - lactide polymerization

KW - organometallic compounds

KW - organocalcium halides

KW - calcium

KW - magnesium

KW - complexes

KW - strontium

KW - zinc

U2 - 10.1021/ic700583e

DO - 10.1021/ic700583e

M3 - Article

SN - 0020-1669

VL - 46

SP - 7686

EP - 7688

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -

Synthesis and structure of a molecular barium aminebis(phenolate) and its application as an initiator for ring-opening polymerization of cyclic esters

Abstract

Keywords

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