Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg]: a new type of magnesiate complex free of a donor solvent as ligand

W. Clegg; Kenneth W. Henderson; Robert Mulvey; P.A. O'Neil

doi:10.1039/C39930000969

Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg]: a new type of magnesiate complex free of a donor solvent as ligand

W. Clegg, Kenneth W. Henderson, Robert Mulvey, P.A. O'Neil

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.

Original language	English
Pages (from-to)	969-970
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	1993
Issue number	11
DOIs	https://doi.org/10.1039/C39930000969
Publication status	Published - 7 Jun 1993

Keywords

aryl compounds
metal alkyl
crystal structure

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@article{56f690c8dec14d66aa5f1fbb80be821c,

title = "Synthesis and structural characterisation of the mixed lithium–magnesium amide, [\{PhCH2(Me2NCH2CH2)N\}4Li2Mg]: a new type of magnesiate complex free of a donor solvent as ligand ",

abstract = "A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [\{PhCH2(Me2NCH2CH2)N\}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.",

keywords = "aryl compounds, metal alkyl, crystal structure",

author = "W. Clegg and Henderson, \{Kenneth W.\} and Robert Mulvey and P.A. O'Neil",

year = "1993",

month = jun,

day = "7",

doi = "10.1039/C39930000969",

language = "English",

volume = "1993",

pages = "969--970",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "11",

}

Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg]: a new type of magnesiate complex free of a donor solvent as ligand . / Clegg, W.; Henderson, Kenneth W.; Mulvey, Robert et al.
In: Journal of the Chemical Society, Chemical Communications, Vol. 1993, No. 11, 07.06.1993, p. 969-970.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg]

T2 - a new type of magnesiate complex free of a donor solvent as ligand

AU - Clegg, W.

AU - Henderson, Kenneth W.

AU - Mulvey, Robert

AU - O'Neil, P.A.

PY - 1993/6/7

Y1 - 1993/6/7

N2 - A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.

AB - A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.

KW - aryl compounds

KW - metal alkyl

KW - crystal structure

U2 - 10.1039/C39930000969

DO - 10.1039/C39930000969

M3 - Article

SN - 0022-4936

VL - 1993

SP - 969

EP - 970

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 11

ER -

Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg]: a new type of magnesiate complex free of a donor solvent as ligand

Abstract

Keywords

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