TY - JOUR
T1 - Synthesis and structural characterisation of the mixed lithium–magnesium amide, [{PhCH2(Me2NCH2CH2)N}4Li2Mg]
T2 - a new type of magnesiate complex free of a donor solvent as ligand
AU - Clegg, W.
AU - Henderson, Kenneth W.
AU - Mulvey, Robert
AU - O'Neil, P.A.
PY - 1993/6/7
Y1 - 1993/6/7
N2 - A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.
AB - A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.
KW - aryl compounds
KW - metal alkyl
KW - crystal structure
U2 - 10.1039/C39930000969
DO - 10.1039/C39930000969
M3 - Article
SN - 0022-4936
VL - 1993
SP - 969
EP - 970
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 11
ER -