Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone

J.F. Allan; K.W. Henderson; A.R. Kennedy; S.J. Teat

doi:10.1039/b002892o

Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone

J.F. Allan, K.W. Henderson, A.R. Kennedy, S.J. Teat

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.

Original language	English
Pages (from-to)	1059-1060
Number of pages	1
Journal	Chemical Communications (London)
Volume	2000
Issue number	12
DOIs	https://doi.org/10.1039/b002892o
Publication status	Published - 26 May 2000

Keywords

magnesium enolate
metals
enolates
ketones

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10.1039/b002892o

Cite this

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title = "Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone",

abstract = "A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.",

keywords = "magnesium enolate, metals, enolates, ketones",

author = "J.F. Allan and K.W. Henderson and A.R. Kennedy and S.J. Teat",

year = "2000",

month = may,

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language = "English",

volume = "2000",

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journal = "Chemical Communications (London)",

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T1 - Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone

AU - Allan, J.F.

AU - Henderson, K.W.

AU - Kennedy, A.R.

AU - Teat, S.J.

PY - 2000/5/26

Y1 - 2000/5/26

N2 - A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.

AB - A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.

KW - magnesium enolate

KW - metals

KW - enolates

KW - ketones

UR - http://dx.doi.org/10.1039/b002892o

U2 - 10.1039/b002892o

DO - 10.1039/b002892o

M3 - Article

SN - 0009-241X

VL - 2000

SP - 1059

EP - 1060

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 12

ER -

Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone

Abstract

Keywords

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Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone

Abstract

Keywords

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