Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone

J.F. Allan, K.W. Henderson, A.R. Kennedy, S.J. Teat

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.
LanguageEnglish
Pages1059-1060
Number of pages1
JournalChemical Communications (London)
Volume2000
Issue number12
DOIs
Publication statusPublished - 26 May 2000

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Addition reactions
Ketones
Magnesium
Metals
Chemical analysis
3-hydroxybutanal

Keywords

  • magnesium enolate
  • metals
  • enolates
  • ketones

Cite this

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Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone. / Allan, J.F.; Henderson, K.W.; Kennedy, A.R.; Teat, S.J.

In: Chemical Communications (London), Vol. 2000, No. 12, 26.05.2000, p. 1059-1060.

Research output: Contribution to journalArticle

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T1 - Synthesis and structural characterisation of a magnesium bisenolate: a tetrameric (Mg2O2)(2) chain terminated by solvating ketone

AU - Allan, J.F.

AU - Henderson, K.W.

AU - Kennedy, A.R.

AU - Teat, S.J.

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N2 - A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.

AB - A reactive magnesium enolate intermediate has been identified containing the remarkable composition of four metals, eight enolates (six bridging and two terminally bound) and two unenolised ketones, and its implications in the aldol addition reaction are discussed.

KW - magnesium enolate

KW - metals

KW - enolates

KW - ketones

UR - http://dx.doi.org/10.1039/b002892o

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DO - 10.1039/b002892o

M3 - Article

VL - 2000

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JO - Chemical Communications (London)

T2 - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

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