Synthesis and properties of alkynethiolate gold(I) complexes

Nora Lardies, Inocencio Romeo, Elena Cerrada, Mariano Laguna, Peter Skabara

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13 Citations (Scopus)

Abstract

A series of alkynethiolate gold(I) derivatives have been synthesised by the cleavage of 4-monosubstituted 1,2,3-thiadiazoles in the presence of strong bases. The syntheses of the 1,2,3-thiadiazoles with p-cyanophenyl, p-tolyl, 2-thienyl, 3-thienyl and 9,9-dimethylfluoren-2-yl fragments are also described. All the complexes have been characterised by spectroscopic techniques and the complexes [Au(p-CH3–C6H4–CC–S)PPh3], [Au(3-C4H3S–CC–S)PPh3] and PPN[Au(p-CH3–C6H4–CC–S)(C6F5)] by X-ray analysis. The electrochemically polymerizable mononuclear bis(alkynethiolate) gold(I) complex PPN[Au(3-C4H3S–CC–S)2] is also described, including its electropolymerization and electrochemical properties.
Original languageUndefined/Unknown
Pages (from-to)5329-5338
Number of pages10
JournalDalton Transactions
Issue number45
DOIs
Publication statusPublished - 2007

Keywords

  • alkynethiolate gold(I) complexes
  • electropolymerization

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